Rhodium(I), rhodium(III) and iridium(III) carbaporphyrins

被引：23

作者：

Adiraju, Venkata A. K. ^{[1
]}

Ferrence, Gregory M. ^{[1
]}

Lash, Timothy D. ^{[1
]}

机构：

[1] Illinois State Univ, Dept Chem, Normal, IL 61790 USA

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 35期

基金：

美国国家科学基金会;

关键词：

N-CONFUSED PORPHYRIN; STRUCTURAL-CHARACTERIZATION; ORGANOMETALLIC COMPLEXES; P-BENZIPORPHYRIN; CARBON-ATOM; AZULIPORPHYRINS; CHEMISTRY; BENZOCARBAPORPHYRINS; PALLADIUM(II); CONTRACTION;

D O I：

10.1039/c6dt03093a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of a benzocarbaporphyrin with [Rh(CO)(2)Cl](2) in refluxing dichloromethane gave a rhodium(I) dicarbonyl complex, and further reaction in refluxing pyridine afforded an organometallic rhodium(III) derivative. The carbaporphyrin also reacted with [Ir(COD)Cl](2) and pyridine in refluxing p-xylene to generate a related iridium(III) compound. These novel metalated porphyrinoids retained strongly diatropic characteristics and were fully characterized by XRD.

引用

页码：13691 / 13694

页数：4

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