Polyborylated reagents for modern organic synthesis

被引：36
作者：
Shimizu, Masaki [1 ]
Hiyama, Tamejiro [1 ]
机构：
[1] Kyoto Univ Katsura, Dept Chem Mat, Grad Sch Engn, Kyoto Univ,Nishikyo Ku, Kyoto 6158510, Japan
来源：
PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES | 2008年 / 84卷 / 03期
关键词：
boron; carbenoid; dimetalated reagents; organic synthesis;
D O I：
10.2183/pjab.84.75
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Diverse kinds of gem- and vic-diborylated compounds are now readily available thanks to advances in gem-diborylation of lithium carbenoids as well as vic-diborylation of carbon-carbon multiple bonds with diboron compounds. These diborylated reagents lead to invention of polyborylated reagents and many novel and useful synthetic methods for supreme stereocontrol. This review summarizes preparative methods and synthetic reactions of di- and polyborylated reagents with the emphasis on multiple bond formation.
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收藏
页码：75 / 85
页数：11
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