Composite Hybrid Cluster Built from the Integration of Polyoxometalate and a Metal Halide Cluster: Synthetic Strategy, Structure, and Properties

被引:56
作者
Li, Xin-Xiong [1 ]
Ma, Xiang [1 ]
Zheng, Wen-Xu [1 ]
Qi, Yan-Jie [1 ]
Zheng, Shou-Tian [1 ]
Yang, Guo-Yu [2 ]
机构
[1] Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujian, Peoples R China
[2] Beijing Inst Technol, Sch Chem, MOE Key Lab Cluster Sci, Beijing 100081, Peoples R China
关键词
ORGANIC FRAMEWORKS; POLYOXOTUNGSTATES; EVOLUTION; WATER; CR;
D O I
10.1021/acs.inorgchem.6b01453
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A step-by-step synthetic strategy, setting up a bridge between the polyoxometalate (POM) and metal halide cluster (MHC) systems, is demonstrated to construct an unprecedented composite hybrid cluster built up from one high-nuclearity cationic MHC [Cu8I6](2+) and eight Anderson-type anionic POMs [HCrMo6O18(OH)(6)](2-) cross-linked by a tripodal alcohol derivative.
引用
收藏
页码:8257 / 8259
页数:3
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