Composite Hybrid Cluster Built from the Integration of Polyoxometalate and a Metal Halide Cluster: Synthetic Strategy, Structure, and Properties

被引：56

作者：

Li, Xin-Xiong ^{[1
]}

Ma, Xiang ^{[1
]}

Zheng, Wen-Xu ^{[1
]}

Qi, Yan-Jie ^{[1
]}

Zheng, Shou-Tian ^{[1
]}

Yang, Guo-Yu ^{[2
]}

机构：

[1] Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujian, Peoples R China

[2] Beijing Inst Technol, Sch Chem, MOE Key Lab Cluster Sci, Beijing 100081, Peoples R China

来源：

INORGANIC CHEMISTRY | 2016年 / 55卷 / 17期

关键词：

ORGANIC FRAMEWORKS; POLYOXOTUNGSTATES; EVOLUTION; WATER; CR;

D O I：

10.1021/acs.inorgchem.6b01453

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A step-by-step synthetic strategy, setting up a bridge between the polyoxometalate (POM) and metal halide cluster (MHC) systems, is demonstrated to construct an unprecedented composite hybrid cluster built up from one high-nuclearity cationic MHC [Cu8I6](2+) and eight Anderson-type anionic POMs [HCrMo6O18(OH)(6)](2-) cross-linked by a tripodal alcohol derivative.

引用

页码：8257 / 8259

页数：3

共 31 条

[1] Thermochromic and Mechanochromic Luminescence Umpolung in Isostructural Metal-Organic Frameworks Based on Cu6I6 Clusters [J].

Deshmukh, Mahesh S. ;

Yadav, Ashok ;

Pant, Rakesh ;

Boomishankar, Ramamoorthy .

INORGANIC CHEMISTRY, 2015, 54 (04) :1337-1345

[2] Recent advances in porous polyoxometalate-based metal-organic framework materials [J].

Du, Dong-Ying ;

Qin, Jun-Sheng ;

Li, Shun-Li ;

Su, Zhong-Min ;

Lan, Ya-Qian .

CHEMICAL SOCIETY REVIEWS, 2014, 43 (13) :4615-4632

[3] Parametrization of the magnetic behavior of the triangular spin ladder chains organically templated:: (C2N2H10)[M(HPO3)F3] (MIII = Fe, Cr, and V).: Crystal structure and thermal and spectroscopic properties of the iron(III) phase [J].

Fernández-Armas, S ;

Mesa, JL ;

Pizarro, JL ;

Clemente-Juan, JM ;

Coronado, E ;

Arriortua, MI ;

Rojo, T .

INORGANIC CHEMISTRY, 2006, 45 (08) :3240-3248

[4] Dye-sensitized polyoxometalate for visible-light-driven photoelectrochemical cells [J].

Gao, Junkuo ;

Miao, Jianwei ;

Li, Yongxin ;

Ganguly, Rakesh ;

Zhao, Yang ;

Lev, Ovadia ;

Liu, Bin ;

Zhang, Qichun .

DALTON TRANSACTIONS, 2015, 44 (32) :14354-14358

[5] Molecule-Based Water-Oxidation Catalysts (WOCs): Cluster-Size-Dependent Dye-Sensitized Polyoxometalates for Visible-Light-Driven O2 Evolution [J].

Gao, Junkuo ;

Cao, Shaowen ;

Tay, Qiuling ;

Liu, Yi ;

Yu, Lingmin ;

Ye, Kaiqi ;

Mun, Peter Choon Sze ;

Li, Yongxin ;

Rakesh, Ganguly ;

Loo, Say Chye Joachim ;

Chen, Zhong ;

Zhao, Yang ;

Xue, Can ;

Zhang, Qichun .

SCIENTIFIC REPORTS, 2013, 3

[6] Luminescent MTN-Type Cluster-Organic Framework with 2.6 nm Cages [J].

Kang, Yao ;

Wang, Fei ;

Zhang, Jian ;

Bu, Xianhui .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (43) :17881-17884

[7] Designed Assembly of Heterometallic Cluster Organic Frameworks Based on Anderson-Type Polyoxometalate Clusters [J].

Li, Xin-Xiong ;

Wang, Yang-Xin ;

Wang, Rui-Hu ;

Cui, Cai-Yan ;

Tian, Chong-Bin ;

Yang, Guo-Yu .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (22) :6462-6466

[8] Surface and Bulk Integrations of Single-Layered Au or Ag Nanoparticles onto Designated Crystal Planes {110} or {100} of ZIF-8 [J].

Li, Zheng ;

Zeng, Hua Chun .

CHEMISTRY OF MATERIALS, 2013, 25 (09) :1761-1768

[9] Step-by-step covalent modification of Cr-templated Anderson-type polyoxometalates [J].

Lin, Chang-Gen ;

Chen, Wei ;

Long, De-Liang ;

Cronin, Leroy ;

Song, Yu-Fei .

DALTON TRANSACTIONS, 2014, 43 (23) :8587-8590

[10] Designable Yolk-Shell Nanoparticle@MOF Petalous Heterostructures [J].

Liu, Yayuan ;

Zhang, Weina ;

Li, Shaozhou ;

Cui, Chenlong ;

Wu, Jin ;

Chen, Hongyu ;

Huo, Fengwei .

CHEMISTRY OF MATERIALS, 2014, 26 (02) :1119-1125

← 1 2 3 4 →