Structures, energetics and spectroscopy of gas phase transition metal ion-benzene complexes

被引：86

作者：

Duncan, Michael A. ^{[1
]}

机构：

[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY | 2008年 / 272卷 / 2-3期

关键词：

organometallic ion; photodissociation; infrared spectroscopy; cluster;

D O I：

10.1016/j.ijms.2008.01.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Metal-benzene complexes provide classic examples of organometallic chemistry, and their ions have similar appeal for mass spectrometry and ion chemistry. This review covers new formation methods for the generation of novel metal ion-benzene complexes and clusters in the gas phase, as well as new measurements of their properties. Collision induced dissociation, radiative decay kinetics and photodissociation methods have been applied to determine bonding energetics, while UV-vis, infrared and photoelectron spectroscopic measurements have been applied to determine structure and bonding patterns. Electronic structure calculations have been pursued to complement these various experiments. This review surveys recent progress in these areas, providing an overview of the field and suggesting future research directions. (c) 2008 Elsevier B.V. All rights reserved.

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收藏

页码：99 / 118

页数：20

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