Synthesis and self-assembly of amphiphilic dendronized conjugated polymers

被引:23
|
作者
Xiao, Xing [1 ]
Wu, Yonggang [1 ]
Sun, Minghao [1 ]
Zhou, Jianjun [1 ]
Bo, Zhishan [1 ]
Li, Lin [1 ]
Chan, Chiming [2 ]
机构
[1] Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, BNLMS,State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
[2] Hong Kong Univ Sci & Technol, Dept Chem Engn, Hong Kong, Hong Kong, Peoples R China
关键词
amphiphilic; amphiphiles; conjugated polymer; dendronized polymer; self-organization; Suzuki polycondensation;
D O I
10.1002/pola.22407
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Two kinds of amphiphilic dendronized conjugated polymers, polyfluorene (PF) and poly(binaphthyl-alt-fluorene) (PBF), were synthesized by Suzuki polycondensation of hydrophobic macromonomers with two nonpolar octyloxy chains and hydrophilic macromonomers with two polar oligo(ethylene oxide) chains. In these polymers, PF possesses a linear rod-like backbone structure, and PBF adopts a folded rigid backbone structure. The different configurations in the conjugated main chains result in different supramolecular self-assembly morphologies. The optical and thermal properties of PF and PBF were also studied. (C ) 2007 Wiley Periodicals, Inc.
引用
收藏
页码:574 / 584
页数:11
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