Pd(II)-Catalyzed Decarboxylative Cross-Coupling of Potassium Aryltrifluoroborates with α-Oxocarboxylic Acids at Room Temperature

被引：114

作者：

Li, Mingzong ^{[1
]}

Wang, Cong ^{[1
]}

Ge, Haibo ^{[1
]}

机构：

[1] Indiana Univ Purdue Univ, Dept Chem & Chem Biol, Indianapolis, IN 46202 USA

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 08期

基金：

美国国家科学基金会;

关键词：

CARBOXYLIC-ACIDS; BORONIC ACIDS; C-H; AROMATIC CARBOXYLATES; CATALYZED SYNTHESIS; KETONE SYNTHESIS; BIARYL SYNTHESIS; ARYL BROMIDES; ACYLATION; PALLADATION;

D O I：

10.1021/ol200459v

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel Pd-catalyzed decarboxylative cross-coupling of potassium aryltrifluoroborates with alpha-oxocarboxylic acids is performed at room temperature. This reaction provides an efficient access to aryl ketones under mild conditions.

引用

页码：2062 / 2064

页数：3

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