TiCl4, dioxane -: A facile and efficient system for De-O-benzylation, De-O-xylyallylation, and De-O-allylation of phenolic ethers

被引：13
作者：
Rajakumar, P [1 ]
Murali, V [1 ]
机构：
[1] Univ Madras, Dept Organ Chem, Madras 600025, Tamil Nadu, India
来源：
SYNTHETIC COMMUNICATIONS | 2003年 / 33卷 / 22期
关键词：
D O I：
10.1081/SCC-120026311
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Simultaneous de-O-xylylation and reductive coupling was observed when I equiv. of the dialdehyde 2a/2b was treated with 5 equiv. of each TiCl4 and Zinc which lead to the development of TiCl4 in dioxane as a new system for the facile deprotection of phenolic ethers 4a-4d, 5a-5d, and 6a-6c.
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页码：3891 / 3896
页数：6
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