Electrochemical methoxylation of some benzaldehyde derivatives at platinum electrode

被引:0
|
作者
Sharma, Laxmi Kant [1 ]
Saraswat, Apoorv [1 ]
Kumar, Hridyesh [1 ]
Srivastav, Manish K. [1 ]
Singh, R. K. P. [1 ]
机构
[1] Univ Allahabad, Dept Chem, Electrochem Lab Green Synth, Allahabad 211002, Uttar Pradesh, India
关键词
Electrochemical methoxylation; constant potential electrolysis; substitution; methoxy free radical; ANODIC-OXIDATION; HOMOLYTIC METHOXYLATION; ELECTROORGANIC SYNTHESIS; AROMATIC-COMPOUNDS; 2-AMINO-5-SUBSTITUTED-1,3,4-OXADIAZOLES;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The electrochemical methoxylation of 4-chlorobenzaldehyde, 4-hydroxybenzaldehyde, 4-anisylaldehyde and 4,4-N,N'-dimethylaminobenzaldehyde was carried out at platinum electrode. Constant potential electrolysis was carried out in undivided electrochemical cell. The reaction is an example of nuclear oxidation of aromatic compounds with substitution. The experimental parameters involved in the reaction are discussed here.
引用
收藏
页码:727 / 730
页数:4
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