Preparation of heterogeneous film from core-shell composite polymer particles produced by the stepwise heterocoagulation method with heat treatment

被引：30
|
作者：
Okubo, M
Lu, Y
机构：
[1] Dept. of Chem. Sci. and Engineering, Faculty of Engineering, Kobe University, Rokko, Nada
来源：
COLLOID AND POLYMER SCIENCE | 1996年 / 274卷 / 11期
关键词：
film; emulsion polymerization; core-shell; stepwise hetero-coagulation; heterogeneous structure;
D O I：
10.1007/BF00658366
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Core-shell composite polymer particle consisting of a hydrophilic core and hydrophobic shell was produced by the stepwise heterocoagulation of small cationic styrene-butyl acrylate-methacryloyoxyethyl trimethylammonium chloride terpolymer particles onto a large anionic methyl methacrylate-ethyl acrylate-methacrylic acid terpolymer particle (LP), which was proposed by the authors in 1990. In order to prepare a film from such a core-shell composite polymer emulsion, the shell content was controlled by changing the diameter of LP and by increasing the methacrylic acid content in LP.
引用
收藏
页码：1020 / 1024
页数：5
相关论文
共 35 条
  • [21] Preparation and characterization of titanium dioxide core/polymer shell hybrid composite particles prepared by emulsion polymerization
    Yu, DG
    An, JH
    Bae, JY
    Lee, YE
    Ahn, SD
    Kang, SY
    Suh, KS
    JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 92 (05) : 2970 - 2975
  • [22] Preparation of Polystyrene/Poly(Methyl Methacrylate) Core-Shell Composite Particles by Suspension-Emulsion Combined Polymerization
    Zhang Zhenqian
    Bao Yongzhong
    Huang Zhiming
    Weng Zhixue
    JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 111 (04) : 1659 - 1669
  • [23] Preparation and characterization of polymer electrolyte membranes based on silicon-containing core-shell structured nanocomposite latex particles
    Zhong, Shuangling
    Sun, Chenggang
    Gao, Yushan
    Cui, Xuejun
    JOURNAL OF POWER SOURCES, 2015, 289 : 34 - 40
  • [24] Preparation and characterization of emulsifier-free core-shell interpenetrating polymer network-fluorinated polyacrylate latex particles
    Cui, Xuejun
    Zhong, Shuangling
    Gao, Yan
    Wang, Hongyan
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 324 (1-3) : 14 - 21
  • [25] Preparation of Poly(butyl acrylate)-Poly(methyl methacrylate) (Core-Shell)/Phosphor Composite Particles and its Application in PVC Matrix
    Chen, Tonghua
    Xu, Peng
    Luo, Yongyue
    Jiang, Long
    Dan, Yi
    Zhang, Li
    Zhao, Kun
    JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 114 (01) : 496 - 502
  • [26] Agglomeration-free core-shell polystyrene/silica particles preparation using an electrospray method and additive-free cationic polystyrene core
    Suhendi, Asep
    Nandiyanto, Asep Bayu Dani
    Ogi, Takashi
    Okuyama, Kikuo
    MATERIALS LETTERS, 2013, 91 : 161 - 164
  • [27] The effect of octamethylcyclotetrasiloxane (D4) addition on the structure and properties of film-forming polyacrylate/silica core-shell composite particles
    Yuan, Junjie
    Qian, He
    JOURNAL OF APPLIED POLYMER SCIENCE, 2015, 132 (22)
  • [28] Construction of heterogeneous core-shell CoFeMo polymetallic sulfide/N-rich carbon skeleton composite catalysts based on stepwise displacement of MOF for overall water splitting
    Chen, Shi
    Zhao, Yueqi
    Chang, Caiyun
    Wang, Xinyi
    Hou, Li
    Jin, Jing
    Gao, Faming
    FUEL, 2024, 365
  • [29] Preparation of core-shell magnetic ion-imprinted polymer for selective extraction of Pb(II) from environmental samples
    Zhang, Minglei
    Zhang, Zhaohui
    Liu, Yunan
    Yang, Xiao
    Luo, Lijuan
    Chen, Jutao
    Yao, Shouzhuo
    CHEMICAL ENGINEERING JOURNAL, 2011, 178 : 443 - 450
  • [30] Microwave-assisted Heating Preparation of Core-shell Ion-imprinted Polymer and Extraction of Cr(III) from Urine
    Zhang Zhao-Hui
    Zhang Ming-Lei
    Xu Tian-Zhen
    Luo Li-Juan
    Yang Xiao
    Yao Shou-Zhuo
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2010, 31 (09): : 1734 - 1740
1234