Evaluation of Corrosion Inhibition of 1018 Carbon Steel using an Avocado Oil-Based Green Corrosion Inhibitor

被引:10
作者
Sotelo-Mazon, O. [1 ]
Valdez, S. [1 ]
Porcayo-Calderon, J. [2 ]
Henao, J. [3 ]
Cuevas-Arteaga, C. [2 ]
Poblano-Salas, C. A. [4 ]
Martinez-Gomez, L. [1 ,5 ]
机构
[1] Univ Nacl Autonoma Mexico, Inst Ciencias Fis, Cuernavaca 62210, Chamilpa, Mexico
[2] Univ Autonoma Estado Morelos, CIICAp, Cuernavaca 62210, Chamilpa, Mexico
[3] CIATEQ AC, CONACYT, Queretaro 76246, El Marques, Mexico
[4] CIATEQ AC, Queretaro 76246, El Marques, Mexico
[5] CyP, Mexico City 11590, Anzures, Mexico
关键词
inhibitor; imidazoline; carbon steel; electrochemical techniques; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; CO2; CORROSION; MILD-STEEL; Q235; STEEL; PIPELINE STEEL; IMIDAZOLINE; BEHAVIOR; HYDROXYETHYL; AMINOETHYL; COCONUT;
D O I
10.1134/S2070205120020240
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The present study is focused on evaluating the corrosion resistance of 1018 carbon steel and the influence of using a corrosion inhibitor in its corrosion behavior. In particular, the corrosion inhibitor prepared in the present study consists in an organic compound of hydroxyethyl-imidazoline derivate based on avocado oil. A mixture of brine-diesel saturated with CO2 was used as a corrosive medium at 70 degrees C. The electrochemical techniques employed to evaluate the performance of the inhibitor were polarization curves, open circuit potential, linear polarization resistance and electrochemical impedance spectroscopy. The results revealed that a high efficiency was obtained when the inhibitor was added in 25 ppm. This fact was supported by scanning electron microscopy, where a uniform corrosion process was observed with the formation of an iron carbonate film. This film was formed when the inhibitor was added in 5, 10 and 25 ppm. However, when the concentrations used were 50 and 100 ppm, a localized corrosion process was promoted. In the present study, some calculations were performed to determinate the chemical adsorption process energy ( = -50.89 kJ/mol) through isotherm adsorption of Langmuir.
引用
收藏
页码:427 / 437
页数:11
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