Calibrated Co3O4 nanoparticles patterned in SBA-15 silicas:: Accessibility and activity for CO oxidation

被引：34
|
作者：
Lopes, I. [1 ]
Davidson, A. [1 ]
Thomas, C. [1 ]
机构：
[1] Univ Paris 06, UMR, CNRS 7609, Lab React Surface, F-75252 Paris, France
来源：
CATALYSIS COMMUNICATIONS | 2007年 / 8卷 / 12期
关键词：
CO oxidation; CO3O4; SBA-15; nanocasting; catalysts; site accessibility;
D O I：
10.1016/j.catcom.2007.04.011
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The catalytic performances in CO oxidation of Co3O4 nanoparticles patterned in the porosity of SBA-15 silicas are investigated. Accessibility limitations of the reactants to the catalytic sites are clearly revealed, when the Co3O4 nanoparticles are embedded in the SBA-15 pores. Despite these limitations, the synthesised Co3O4 nanoparticles exhibit promising CO oxidation properties. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：2105 / 2109
页数：5
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