Characterization of steel slag for the production of chemically bonded phosphate ceramics (CBPC)

被引:20
作者
Cardenas Balaguera, Carlos Andres [1 ,2 ]
Gomez Botero, Maryory Astrid [1 ]
机构
[1] Univ Antioquia UdeA, Fac Ingn, Ctr Invest Innovac & Desarrollo Mat CIDEMAT, Calle 70 52-21, Medellin, Colombia
[2] UPTC, Diseno Innovac & Asistencia Tecn Mat Avanzados DI, Ave Cent Norte 39-115, Tunja, Colombia
关键词
Characterization; Chemically bonded phosphate ceramics; Steel slag; Metallic oxides; Mechanical properties; MECHANICAL-PROPERTIES; WATER-RESISTANCE; FURNACE; DURABILITY; POTASSIUM; CEMENT; WOLLASTONITE; CONCRETE; MODEL; RAMAN;
D O I
10.1016/j.conbuildmat.2020.118138
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
This work studies the use of steel slag as a source of metallic oxides for the synthesis of chemically bonded phosphate ceramics (CBPCs). Analysis of different slags revealed characteristics, relating to alkaline character, granulometry and metallic oxide content, which could enable their use other than as construction aggregates. Steel slags from an electric arc furnace (EAF) and basic oxygen furnace (BOF), as well as ladle furnace basic slag (LFS), were collected from steel plants in Colombia following the ASTM D75 standard practice for aggregate sampling. The slags were analysed through techniques such as SEM/EDS, FTIR, XRD and XRF, finding considerable quantities of CaO and iron oxides that provide the necessary metallic cation in acid-base reaction systems. The formation of phosphate ceramics was achieved from steel slags, compression strengths of up to 20 MPa were reached at 35 days and the chemical stability of the cements obtained was evaluated. Additionally, physical properties important to the formation of chemically bonded phosphate ceramics (CBPCs), such as specific gravity, grain size and pH, were determined. (C) 2020 Elsevier Ltd. All rights reserved.
引用
收藏
页数:11
相关论文
共 56 条
[1]  
Agudelo J., 2000, REV FAC ING-UNIV ANT, V21, P77
[2]   Production of monetite-based Inorganic Phosphate Cement (M-IPC) using hydrothermal post curing (HTPC) [J].
Alshaaer, M. ;
Cuypers, H. ;
Rahier, H. ;
Wastiels, J. .
CEMENT AND CONCRETE RESEARCH, 2011, 41 (01) :30-37
[3]   Evaluation of a low temperature hardening Inorganic Phosphate Cement for high-temperature applications [J].
Alshaaer, M. ;
Cuypers, H. ;
Mosselmans, G. ;
Rahier, H. ;
Wastiels, J. .
CEMENT AND CONCRETE RESEARCH, 2011, 41 (01) :38-45
[4]  
[Anonymous], [No title captured], Patent No. 5830815
[5]  
Attfield J.P., 2001, Encyclopedia of Materials: Science and Technology, VSecond, P6896, DOI [DOI 10.1016/B0-08-043152-6/01222-, 10.1016/B0-08-043152-6/01222-5, DOI 10.1016/B0-08-043152-6/01222-5]
[6]   Influence of steel slag on the mechanical properties and curing time of metakaolin geopolymer [J].
Bai, Tao ;
Song, Zi-Ge ;
Wu, Yan-Guang ;
Hu, Xiao-Di ;
Bai, Hua .
CERAMICS INTERNATIONAL, 2018, 44 (13) :15706-15713
[7]   Development of iron phosphate ceramic waste form to immobilize radioactive waste solution [J].
Choi, Jongkwon ;
Um, Wooyong ;
Choung, Sungwook .
JOURNAL OF NUCLEAR MATERIALS, 2014, 452 (1-3) :16-23
[8]   Effect of curing regime on water resistance of magnesium-potassium phosphate cement [J].
Chong, Linlin ;
Yang, Jianming ;
Shi, Caijun .
CONSTRUCTION AND BUILDING MATERIALS, 2017, 151 :43-51
[9]  
Chukanov N.V., 2014, Infrared spectra of mineral rocks, P1736, DOI 10.1007/978-94-007-7128-4
[10]   Wollastonite based-Chemically Bonded Phosphate Ceramics with lead oxide contents under gamma irradiation [J].
Colorado, H. A. ;
Pleitt, J. ;
Hiel, C. ;
Yang, J. M. ;
Hahn, H. T. ;
Castano, C. H. .
JOURNAL OF NUCLEAR MATERIALS, 2012, 425 (1-3) :197-204