Semiconductor-mediated photodegradation of pollutants under visible-light irradiation

被引:2098
作者
Chen, Chuncheng [1 ]
Ma, Wanhong [1 ]
Zhao, Jincai [1 ]
机构
[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China
关键词
DYE-SENSITIZED TIO2; ELECTRON-TRANSFER DYNAMICS; PHOTOCATALYTIC DEGRADATION; TIO2-ASSISTED PHOTODEGRADATION; PHOTOASSISTED DEGRADATION; TITANIUM-DIOXIDE; CHARGE-TRANSFER; SOLAR-CELLS; RHODAMINE-B; ENVIRONMENTAL PHOTOCHEMISTRY;
D O I
10.1039/b921692h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The semiconductor and the surface-adsorbed antenna molecule (dyes or other color species) can constitute efficient photochemical systems for environmental remediation. The major advantage of these systems is that they are able to achieve the degradation of organic pollutants by using visible light from the sun as energy and O-2 in the air as the oxidant under ambient conditions. In this tutorial review, the unique mechanistic characteristics, the constitution of photodegradation systems and their performance are described. The involved radical reactions during the degradation are also discussed.
引用
收藏
页码:4206 / 4219
页数:14
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