Zeolite A membranes for use in alcohol/water separations - Part I: Experimental investigation

被引：18
作者：
Holmes, SM
Schmitt, M
Markert, C
Plaisted, RJ
Forrest, JO
Sharratt, PN
Garforth, AA
Cundy, CS
Dwyer, J
机构：
[1] Univ Manchester, Inst Sci & Technol, Dept Chem Engn, Ctr Microporous Mat, Manchester M60 1QD, Lancs, England
[2] Univ Manchester, Inst Sci & Technol, Dept Chem, Ctr Microporous Mat, Manchester M60 1QD, Lancs, England
来源：
CHEMICAL ENGINEERING RESEARCH & DESIGN | 2000年 / 78卷 / A8期
基金：
英国工程与自然科学研究理事会;
关键词：
zeolite; membrane; silicalite; zeolite A; alcohol/water separations;
D O I：
10.1205/026387600528355
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Controlled hydrothermal growth on an ultrasonically-anchored nanocrystal precursor layer has provided a route to coherent zeolite A membranes on sintered stainless steel supports. High water selectivity is demonstrated in measurements of fluxes through the membrane using 80-98 mass % ethanol/water mixtures at temperatures of 25-60 degreesC. The use of the hydrophobic/hydrophilic properties of molecular sieve zeolites to separate alcohol water mixtures is discussed.
引用
收藏
页码：1084 / 1088
页数：5
相关论文
共 30 条
  • [21] NEW ONE-DIMENSIONAL MEMBRANE - ALIGNED ALPO4-5 MOLECULAR-SIEVE CRYSTALS IN A NICKEL FOIL
    NOACK, M
    KOLSCH, P
    VENZKE, D
    TOUSSAINT, P
    CARO, J
    [J]. MICROPOROUS MATERIALS, 1994, 3 (1-2): : 201 - 206
  • [22] NOACK M, 1994, J CHEM SOC CHEM COMM, P2491
  • [23] Ethanol/water transport through silicalite membranes
    Nomura, M
    Yamaguchi, T
    Nakao, S
    [J]. JOURNAL OF MEMBRANE SCIENCE, 1998, 144 (1-2) : 161 - 171
  • [24] Membrane occluded catalysts: A higher order mimic with improved performance
    Parton, RF
    Vankelecom, IFJ
    Tas, D
    Janssen, KBM
    KnopsGerrits, PP
    Jacobs, PA
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 113 (1-2) : 283 - 292
  • [25] SEPARATION OF METHANOL/METHYL-TERT-BUTYL ETHER MIXTURE BY PERVAPORATION USING SILICALITE MEMBRANE
    SANO, T
    HASEGAWA, M
    KAWAKAMI, Y
    YANAGISHITA, H
    [J]. JOURNAL OF MEMBRANE SCIENCE, 1995, 107 (1-2) : 193 - 196
  • [26] Separation of acetic acid-water mixtures by pervaporation through silicalite membrane
    Sano, T
    Ejiri, S
    Yamada, K
    Kawakami, Y
    Yanagishita, H
    [J]. JOURNAL OF MEMBRANE SCIENCE, 1997, 123 (02) : 225 - 233
  • [27] The growth of sub-micron films of TPA-silicalite-1 on single crystal silicon wafers from low-temperature clear solutions
    Schoeman, BJ
    Erdem-Senatalar, A
    Hedlund, J
    Sterte, J
    [J]. ZEOLITES, 1997, 19 (01): : 21 - 28
  • [28] Preparation and characterization of hollow fibers of silicalite-1
    Valtchev, V
    Schoeman, B
    Hedlund, J
    Mintova, S
    Sterte, J
    [J]. ZEOLITES, 1996, 17 (5-6): : 408 - 415
  • [29] Deposition of continuous silicalite-1 films on inorganic fibers
    Valtchev, V
    Hedlund, J
    Schoeman, BJ
    Sterte, J
    Mintova, S
    [J]. MICROPOROUS MATERIALS, 1997, 8 (1-2): : 93 - 101
  • [30] VANBEKKUM H, 1994, ADV ZEOLITE SCI APPL
123