Zeolite A membranes for use in alcohol/water separations - Part I: Experimental investigation

被引:18
作者
Holmes, SM
Schmitt, M
Markert, C
Plaisted, RJ
Forrest, JO
Sharratt, PN
Garforth, AA
Cundy, CS
Dwyer, J
机构
[1] Univ Manchester, Inst Sci & Technol, Dept Chem Engn, Ctr Microporous Mat, Manchester M60 1QD, Lancs, England
[2] Univ Manchester, Inst Sci & Technol, Dept Chem, Ctr Microporous Mat, Manchester M60 1QD, Lancs, England
基金
英国工程与自然科学研究理事会;
关键词
zeolite; membrane; silicalite; zeolite A; alcohol/water separations;
D O I
10.1205/026387600528355
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Controlled hydrothermal growth on an ultrasonically-anchored nanocrystal precursor layer has provided a route to coherent zeolite A membranes on sintered stainless steel supports. High water selectivity is demonstrated in measurements of fluxes through the membrane using 80-98 mass % ethanol/water mixtures at temperatures of 25-60 degreesC. The use of the hydrophobic/hydrophilic properties of molecular sieve zeolites to separate alcohol water mixtures is discussed.
引用
收藏
页码:1084 / 1088
页数:5
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