A magnesium-carboxylate framework showing luminescent sensing for CS2 and nitroaromatic compounds

被引：26

作者：

Wu, Zhao-Feng ^{[1
,2
]}

Tan, Bin ^{[1
,2
]}

Feng, Mei-Ling ^{[1
]}

Du, Cheng-Feng ^{[1
,2
]}

Huang, Xiao-Ying ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2015年 / 223卷

关键词：

Magnesium; Metal-organic framework; Luminescent sensing; Carbon disulfide; Nitro explosives; METAL-ORGANIC FRAMEWORK; GAS-ADSORPTION; COORDINATION; FLUORESCENCE; CONDENSATION; CAGES; MOF;

D O I：

10.1016/j.jssc.2014.06.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A magnesium metal-organic framework compound, namely [NH2(CH3)(2)][Mg-3(NDC)(2.5)(HCO2)(2)(DMF)(0.75) (H2O)(0.25)] center dot 1.25DMF center dot 0.75H(2)O (1) (H2NDC= 1,4-naphthalene dicarboxylic acid, DMF=N,N'-dimethylformamide), has been synthesized in solvothermal conditions and structurally characterized. It features a three-dimensionally anionic framework with aligned channels parallel to the b-axis. Luminescent studies indicated that it showed significant luminescence quenching for carbon disulfide (CS2) and nitrobenzene after being activated, at a content of only 3.0 and 0.1 vol% in DMF, respectively. In addition, the activated sample showed sensitive luminescence quenching for 1,3,5-trinitrophenol with a low concentration of 5 x 10(-5) mol/L. (C) 2014 Elsevier Inc. All rights reserved.

引用

页码：59 / 64

页数：6

共 33 条

[1]

[Anonymous], ANGEW CHEM INT ED

[2]

[Anonymous], CHEM SOC REV

[3] Vapor phase detection of nitroaromatic and nitroaliphatic explosives by fluorescence active metal-organic frameworks [J].

Banerjee, Debasis ;

Hu, Zhichao ;

Pramanik, Sanhita ;

Zhang, Xiao ;

Wang, Hao ;

Li, Jing .

CRYSTENGCOMM, 2013, 15 (45) :9745-9750

[4] Light cured networks containing metal organic frameworks as efficient and durable polymer electrolytes for dye-sensitized solar cells [J].

Bella, Federico ;

Bongiovanni, Roberta ;

Kumar, R. Senthil ;

Kulandainathan, M. Anbu ;

Stephan, A. Manuel .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (32) :9033-9036

[5] High capacity CO2 adsorption in a Mg(II)-based phosphine oxide coordination material [J].

Bohnsack, Alisha M. ;

Ibarra, Ilich A. ;

Hatfield, Peter W. ;

Yoon, Ji Woong ;

Hwang, Young Kyu ;

Chang, Jong-San ;

Humphrey, Simon M. .

CHEMICAL COMMUNICATIONS, 2011, 47 (17) :4899-4901

[6] Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites [J].

Britt, David ;

Furukawa, Hiroyasu ;

Wang, Bo ;

Glover, T. Grant ;

Yaghi, Omar M. .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (49) :20637-20640

[7] A luminescent microporous metal-organic framework for the recognition and sensing of anions [J].

Chen, Banglin ;

Wang, Liangbo ;

Zapata, Fatima ;

Qian, Guodong ;

Lobkovsky, Emil B. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (21) :6718-+

[8] Luminescent Functional Metal-Organic Frameworks [J].

Cui, Yuanjing ;

Yue, Yanfeng ;

Qian, Guodong ;

Chen, Banglin .

CHEMICAL REVIEWS, 2012, 112 (02) :1126-1162

[9] Strong H2 binding and selective gas adsorption within the microporous coordination solid Mg3(O2C-C10H6-CO2)3 [J].

Dinca, M ;

Long, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (26) :9376-9377

[10] Magnesium-Based 3D Metal-Organic Framework Exhibiting Hydrogen-Sorption Hysteresis [J].

Guo, Zhiyong ;

Li, Guanghua ;

Zhou, Liang ;

Su, Shenqqun ;

Lei, Yongqian ;

Dang, Song ;

Zhang, Hongjie .

INORGANIC CHEMISTRY, 2009, 48 (17) :8069-8071

← 1 2 3 4 →