Ultrafast energy-transfer dynamics in a blend of electroluminescent conjugated polymers

被引:36
作者
Cerullo, G [1 ]
Nisoli, M
Stagira, S
De Silvestri, S
Lanzani, G
Graupner, W
List, E
Leising, G
机构
[1] Politecn Milan, CEQSE,CNR, Ist Nazl Fis Mat, Dipartimento Fis, I-20133 Milan, Italy
[2] Univ Sassari, Inst Matemat & Fis, I-07100 Sassari, Italy
[3] Graz Tech Univ, Inst Festkorperphys, A-8010 Graz, Austria
关键词
D O I
10.1016/S0009-2614(98)00337-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Femtosecond pump-probe spectroscopy was applied to a guest-host system of conjugated polymers, the blue-emitting poly(para-phenylene) (m-LPPP) and the red-emitting poly(perylene-co-diethynylbenzene) (PPDB). Excitation energy transfer between m-LPPP and PPDB, monitored by the formation of the PPDB photobleaching band at 2.15 eV, takes place on a picosecond timescale. The non-exponential kinetics of the excitation energy transfer and its dependence on the acceptor (PPDB) concentration provide clear evidence for a Forster-type energy transfer. (C) 1998 published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码:561 / 566
页数:6
相关论文
共 21 条
[1]  
Berggren M, 1997, NATURE, V389, P466
[2]   DYNAMICS OF EXCITATION TRANSFER IN DYE-DOPED PI-CONJUGATED POLYMERS [J].
BOLIVAR, PH ;
WEGMANN, G ;
KERSTING, R ;
DEUSSEN, M ;
LEMMER, U ;
MAHRT, RF ;
BASSLER, H ;
GOBEL, EO ;
KURZ, H .
CHEMICAL PHYSICS LETTERS, 1995, 245 (06) :534-538
[3]   VISIBLE-LIGHT EMISSION FROM SEMICONDUCTING POLYMER DIODES [J].
BRAUN, D ;
HEEGER, AJ .
APPLIED PHYSICS LETTERS, 1991, 58 (18) :1982-1984
[4]   LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].
BURROUGHES, JH ;
BRADLEY, DDC ;
BROWN, AR ;
MARKS, RN ;
MACKAY, K ;
FRIEND, RH ;
BURN, PL ;
HOLMES, AB .
NATURE, 1990, 347 (6293) :539-541
[5]  
CERULLO G, IN PRESS PHYS REV B
[6]   Factors influencing stimulated emission from poly(p-phenylenevinylene) [J].
Denton, GJ ;
Tessler, N ;
Harrison, NT ;
Friend, RH .
PHYSICAL REVIEW LETTERS, 1997, 78 (04) :733-736
[7]   *ZWISCHENMOLEKULARE ENERGIEWANDERUNG UND FLUORESZENZ [J].
FORSTER, T .
ANNALEN DER PHYSIK, 1948, 2 (1-2) :55-75
[8]   Femtosecond relaxation of photoexcitations in a poly(para-phenylene)-type ladder polymer [J].
Graupner, W ;
Leising, G ;
Lanzani, G ;
Nisoli, M ;
DeSilvestri, S ;
Scherf, U .
PHYSICAL REVIEW LETTERS, 1996, 76 (05) :847-850
[9]  
GRAUPNER W, 1997, 43 SOC PLAST ENG, P1449
[10]   ELECTROLUMINESCENCE OF PURE POLY(N-VINYLCARBAZOLE) AND ITS BLENDS WITH A MULTIBLOCK COPOLYMER [J].
HU, B ;
YANG, Z ;
KARASZ, FE .
JOURNAL OF APPLIED PHYSICS, 1994, 76 (04) :2419-2422