Improved designs of metal-organic frameworks for hydrogen storage

被引：205

作者：

Han, Sang Soo ^{[1
]}

Deng, Wei-Qiao ^{[1
]}

Goddard, William A., III ^{[1
]}

机构：

[1] Nanyang Technol Univ, Singapore, Singapore

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 33期

关键词：

beryllium; hydrogen storage; magnesium; metal-organic frameworks; zinc;

D O I：

10.1002/anie.200700303

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Quick on the uptake: The metal-organic framework Mg-MOF-C30 (see picture) contains Mg4O(CO2)6 building units (pink) and aromatic organic linkers containing 30 carbon atoms (teal). This material leads to 8.08 wt% H2 uptake at 77 K and 20 bar, the highest among investigated MOF structures. (Figure Presented) © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：6289 / 6292

页数：4

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