Synthesis of High-Quality and Self-assembled Cu2ZnSnS4 Nanocrystals

被引:0
作者
Wang Xiao [1 ]
Liu Da-Peng [1 ]
Song Shu-Yan [1 ]
Liu Yong-Xin [1 ]
Zhang Hong-Jie [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resoure Utilizat, Changchun 130022, Peoples R China
关键词
Cu2ZnSnS4; nanocrystals; hot-injection; self-assembly; SOLAR-CELLS; FILM; PHOTOVOLTAICS; CONVERSION;
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
High-quality Cu2ZnSnS4 nanocrystals with narrow size distribution were prepared via a facile hot-injection route by using simple inorganic metallic salt Cu(OAc)(2), Zn(OAc)(2) and SnCl4 as raw materials, stearic acid and octadecylamine as capping molecules and diphenyl ether as solvent. In this paper, we have studied in depth for the influence on the morphologies of the nanocrystals by changing the ratio of stearic acid and octadecylamine. It is shown that Cu2ZnSnS4 nanocrystals grow bigger and have complex nanostructures by increasing the amount of stearic acid. And this material has a strong absorption under the whole region from UV to visible lights. It is believed that Cu2ZnSnS4 has a potential application in photovoltaic devices.
引用
收藏
页码:259 / 263
页数:5
相关论文
共 22 条
  • [1] Bao Zuguo, 2010, Electronic Components & Materials, V29, P64, DOI 10.3969/j.issn.1001-2028.2010.06.019
  • [2] Formation of monodisperse and shape-controlled MnO nanocrystals in non-injection synthesis: Self-focusing via
    Chen, Yongfen
    Johnson, Eric
    Peng, Xiaogang
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (35) : 10937 - 10947
  • [3] Fan SH, 2008, CHINESE J INORG CHEM, V24, P1206
  • [4] GAO P, 2010, ELECT POWER TECHNOLO, V19, P26
  • [5] Solar energy conversion toward 1 terawatt
    Ginley, David
    Green, Martin A.
    Collins, Reuben
    [J]. MRS BULLETIN, 2008, 33 (04) : 355 - 364
  • [6] Synthesis of Cu2ZnSnS4 Nanocrystal Ink and Its Use for Solar Cells
    Guo, Qijie
    Hillhouse, Hugh W.
    Agrawal, Rakesh
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (33) : 11672 - +
  • [7] Cu2ZnSnS4-type thin film solar cells using abundant materials
    Jimbo, Kazuo
    Kimura, Ryoichi
    Kamimura, Tsuyoshi
    Yamada, Satoru
    Maw, Win Shwe
    Araki, Hideaki
    Oishi, Koichiro
    Katagiri, Hironorl
    [J]. THIN SOLID FILMS, 2007, 515 (15) : 5997 - 5999
  • [8] Cu2ZnSnS4 thin film solar cells
    Katagiri, H
    [J]. THIN SOLID FILMS, 2005, 480 : 426 - 432
  • [9] Development of thin film solar cell based on Cu2ZnSnS4 thin films
    Katagiri, H
    Saitoh, K
    Washio, T
    Shinohara, H
    Kurumadani, T
    Miyajima, S
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2001, 65 (1-4) : 141 - 148
  • [10] Preparation and characterization of spray-deposited Cu2ZnSnS4 thin films
    Kumar, Y. B. Kishore
    Babu, G. Suresh
    Bhaskar, P. Uday
    Raja, V. Sundara
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2009, 93 (08) : 1230 - 1237