Exploring The Cr2+ Doping Effect On Structural, Vibrational And Dielectric Properties Of Mn-Zn Ferrites

被引:3
作者
Choudhary, Pankaj [1 ]
Tyagi, Tarun [2 ]
Dar, M. A. [1 ]
Varshney, Dinesh [1 ]
机构
[1] Devi Ahilya Univ, Sch Phys, Vigyan Bhavan, Khandwa Rd Campus, Indore 452001, Madhya Pradesh, India
[2] Amity Univ, Amity Inst Nanotechnol, Sect 125, Noida 201303, India
来源
DAE SOLID STATE PHYSICS SYMPOSIUM 2015 | 2016年 / 1731卷
关键词
Polycrystalline; X-ray diffraction; Raman; Dielectric; MAGNETIC-PROPERTIES;
D O I
10.1063/1.4947972
中图分类号
O59 [应用物理学];
学科分类号
摘要
A series of Cr doped Mn-Zn ferrites with compositional formula Mn0.5Zn0.5-xCrxFe2O4 (x = 0, 0.3, 0.5) were prepared by solid-state reaction route. X-ray diffraction (XRD) analysis reveals that the samples prepared are polycrystalline cubic spinel in structure (Fd3m) with some secondary phase of alpha-Fe2O3. Slight variation in the lattice parameter of Cr doped Mn0.5Zn0.5Fe2O4 has been observed due to difference in ionic radii of cations. Small shift in Raman modes towards higher wave number has been observed. Further the line width decreases with the doping ions. A giant dielectric constant similar to 10(4) is observed for parent Mn0.5Zn0.5Fe2O4 which is found to decrease with increase in Cr2+ doping. Low dielectric loss is observed for Mn0.5Zn0.5Fe2O4 and improves with Cr2+ doping at Zn2+ site.
引用
收藏
页数:3
相关论文
共 10 条
[1]   Magnetic properties of CoFe1.9RE0.1O4 nanoparticles (RE = La, Ce, Nd, Sm, Eu, Gd, Tb, Ho) prepared in polyol [J].
Ben Tahar, L. ;
Artus, M. ;
Ammar, S. ;
Smiri, L. S. ;
Herbst, F. ;
Vaulay, M. -J. ;
Richard, V. ;
Greneche, J. -M. ;
Villain, F. ;
Fievet, F. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2008, 320 (23) :3242-3250
[2]   Structural and magnetic properties of nano-crystalline Ni-Zn ferrites synthesized using egg-white precursor [J].
Gabal, M. A. ;
El-Shishtawy, Reda M. ;
Al Angari, Y. M. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2012, 324 (14) :2258-2264
[3]   Raman study of stoichiometric and Zn-doped Fe3O4 -: art. no. 104430 [J].
Gupta, R ;
Sood, AK ;
Metcalf, P ;
Honig, JM .
PHYSICAL REVIEW B, 2002, 65 (10) :1044301-1044308
[4]   Heat treatment effects on microstructure and magnetic properties of Mn-Zn ferrite powders [J].
Hu, Ping ;
Yang, Hai-bo ;
Pan, De-an ;
Wang, Hua ;
Tian, Jian-jun ;
Zhang, Shen-gen ;
Wang, Xin-feng ;
Volinsky, Alex A. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2010, 322 (01) :173-177
[5]   Synthesis and characterization of surfactant-coated superparamagnetic monodispersed iron oxide nanoparticles [J].
Kim, DK ;
Zhang, Y ;
Voit, W ;
Rao, KV ;
Muhammed, M .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2001, 225 (1-2) :30-36
[6]   ON THE DISPERSION OF RESISTIVITY AND DIELECTRIC CONSTANT OF SOME SEMICONDUCTORS AT AUDIOFREQUENCIES [J].
KOOPS, CG .
PHYSICAL REVIEW, 1951, 83 (01) :121-124
[7]   ac electrical conductivity and dielectric behavior of nanophase nickel ferrites [J].
Mahalakshmi, S. ;
Manja, K. Srinivasa .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 457 (1-2) :522-525
[8]   A study of nanocrystalline (Mn-Zn) ferrite in SiO2 matrix [J].
Mandal, K ;
Mandal, SP ;
Agudo, P ;
Pal, M .
APPLIED SURFACE SCIENCE, 2001, 182 (3-4) :386-389
[9]   Magnetic properties of MnZn ferrites prepared by soft chemical routes [J].
Razzitte, AC ;
Jacobo, SE ;
Fano, WG .
JOURNAL OF APPLIED PHYSICS, 2000, 87 (09) :6232-6234
[10]   Structural and vibrational properties of ZnxMn1-xFe2O4 (x=0.0, 0.25, 0.50, 0.75, 1.0) mixed ferrites [J].
Varshney, Dinesh ;
Verma, Kavita ;
Kumar, Ashwini .
MATERIALS CHEMISTRY AND PHYSICS, 2011, 131 (1-2) :413-419