Improving Nanoparticle Dispersion and Charge Transfer in Cadmium Telluride Tetrapod and Conjugated Polymer Blends

被引:7
作者
Monson, Todd C. [1 ]
Hollars, Christopher W. [2 ,3 ]
Orme, Christine A. [4 ]
Huser, Thomas [3 ,5 ]
机构
[1] Sandia Natl Labs, Albuquerque, NM 87185 USA
[2] MRIGlobal, Kansas City, MO 64110 USA
[3] Univ Calif Davis, NSF Ctr Biophoton Sci & Technol, Sacramento, CA 95817 USA
[4] Lawrence Livermore Natl Lab, Phys & Life Sci Directorate, Livermore, CA 94551 USA
[5] Univ Calif Davis, Dept Internal Med, Sacramento, CA 95817 USA
关键词
conjugated polymers; polymer composites; semiconductor nanoparticles; confocal fluorescence microscope; AFM; fluoresence; THIN-FILM TRANSISTORS; FIELD-EFFECT MOBILITY; PHOTOVOLTAIC CELLS; MOLECULAR-WEIGHT; SOLAR-CELLS; DEVICES; NANOCRYSTALS; MORPHOLOGY; GROWTH; LAYER;
D O I
10.1021/am101218m
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The dispersion of CdTe tetrapods in a conducting polymer and the resulting charge transfer is studied using a combination of confocal fluorescence microscopy and atomic force microscopy (AFM). The results of this work show that both the tetrapod dispersion and charge transfer between the CdTe and conducting polymer (P3HT) are greatly enhanced by exchanging the ligands on the surface of the CdTe and by choosing proper solvent mixtures. The ability to experimentally probe the relationship between particle dispersion and charge transfer through the combination of AFM and fluorescence microscopy provides another avenue to assess the performance of polymer/semiconductor nanoparticle composites.
引用
收藏
页码:1077 / 1082
页数:6
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