Differential nitrogen-carbon bond cleavages in architecturally complex molecular scaffolds containing a bridge-head nitrogen atom

被引：1

作者：

Chatterjee, Sankar ^{[1
]}

Shamma, Maurice ^{[1
]}

机构：

[1] Penn State Univ, Dept Chem, University Pk, PA 16802 USA

来源：

COMPTES RENDUS CHIMIE | 2015年 / 18卷 / 02期

关键词：

Heterocyclic; Benzazepine; Tetrahydroprotoberberine; Steric; Electronic; TRANSFORMATION;

D O I：

10.1016/j.crci.2014.04.006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Application of an N-C bond cleavage reaction in various structurally complex molecular frameworks containing bridge-head nitrogen atom offered differential outcomes that were attempted to rationalize invoking both steric and electronic factors. (C) 2014 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.

引用

页码：127 / 131

页数：5

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