EXCELLENT ELECTROCHEMICAL BEHAVIOR OF LiMn2O4 IN AQUEOUS ELECTROLYTE

被引：17

作者：

Qu, Quting ^{[1
,2
]}

Wang, Gaojun ^{[1
,2
]}

Liu, Lili ^{[1
,2
]}

Tian, Sshu ^{[1
,2
]}

Shi, Yi ^{[1
,2
]}

Wu, Yuping ^{[1
,2
]}

Holze, Rudolf ^{[3
]}

机构：

[1] Fudan Univ, Dept Chem, NEML, Shanghai 200433, Peoples R China

[2] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

[3] Tech Univ Chemnitz, Inst Chem, AG Elektrochem, D-09107 Chemnitz, Germany

来源：

FUNCTIONAL MATERIALS LETTERS | 2010年 / 3卷 / 03期

关键词：

Aqueous rechargeable lithium battery (ARLB); aqueous solution; cathode; LiMn2O4; RECHARGEABLE LITHIUM BATTERY; GOOD CYCLING PERFORMANCE; INTERCALATION; SYSTEM; LICOO2; LIV3O8;

D O I：

10.1142/S1793604710001135

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

LiMn2O4 was prepared by a solid-state reaction, and for the first time its electrochemical behavior in the organic and aqueous electrolytes were compared. Since the host structure is the same, the intercalation and deintercalation behavior does not change, and the diffusion coefficient of Li+ ions are in the same range. However, due to much higher ionic conductivity of the aqueous electrolyte, its reversible redox behavior at high scan rate is much better than in the organic electrolyte. The reversible capacity in the aqueous electrolyte is 85mAh.g(-1) at the current density of 50mA.g(-1), and 22mAh.g(-1) (26% of the normal capacity) when the current density is up to 10,000mA.g(-1) (118 C). This shows that aqueous rechargeable lithium battery (ARLB) have very high-power density or excellent rate capability, and good cycling behavior.

引用

页码：151 / 154

页数：4

共 15 条

[1]

Bard A.J., 2005, ELECTROCHEMICAL METH, V2nd

[2]

Cao C., 2002, An Introduction to Electrochemical Impedance Spectroscopy, V1

[3] RECHARGEABLE LITHIUM BATTERIES WITH AQUEOUS-ELECTROLYTES [J].

LI, W ;

DAHN, JR ;

WAINWRIGHT, DS .

SCIENCE, 1994, 264 (5162) :1115-1118

[4] Mechanism of the electrochemical insertion of lithium into LiMn2O4 spinels [J].

Liu, W ;

Kowal, K ;

Farrington, GC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (02) :459-465

[5] Electric states of spinel LixMn2O4 as a cathode of the rechargeable battery [J].

Miura, K ;

Yamada, A ;

Tanaka, M .

ELECTROCHIMICA ACTA, 1996, 41 (02) :249-256

[6] Improvement of the rate capability of LiMn2O4 by surface coating with LiCoO2 [J].

Park, SC ;

Kim, YM ;

Kang, YM ;

Kim, KT ;

Lee, PS ;

Lee, JY .

JOURNAL OF POWER SOURCES, 2001, 103 (01) :86-92

[7] Manganese oxides for lithium batteries [J].

Thackeray, MM .

PROGRESS IN SOLID STATE CHEMISTRY, 1997, 25 (1-2) :1-71

[8] Aqueous rechargeable lithium battery (ARLB) based on LiV3O8 and LiMn2O4 with good cycling performance [J].

Wang, G. J. ;

Zhang, H. P. ;

Fu, L. J. ;

Wang, B. ;

Wu, Y. P. .

ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (08) :1873-1876

[9] An aqueous rechargeable lithium battery based on doping and intercalation mechanisms [J].

Wang, G. J. ;

Yang, L. C. ;

Qu, Q. T. ;

Wang, B. ;

Wu, Y. P. ;

Holze, R. .

JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2010, 14 (05) :865-869

[10] Electrochemical intercalation of lithium ions into LiV3O8 in an aqueous electrolyte [J].

Wang, G. J. ;

Qu, Q. T. ;

Wang, B. ;

Shi, Y. ;

Tian, S. ;

Wu, Y. P. ;

Holze, R. .

JOURNAL OF POWER SOURCES, 2009, 189 (01) :503-506

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