Synthesis and electrocatalytic properties of a dinuclear copper(II) complex for generating hydrogen from acetic acid or water

被引：12

作者：

Fang, Ting ^{[1
]}

Li, Wei ^{[2
]}

Zhan, Shu-Zhong ^{[1
]}

Wei, Xiao-Lan ^{[1
]}

机构：

[1] S China Univ Technol, Coll Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R China

[2] Guizhou Minzu Univ, Sch Chem & Environm Sci, Guiyang, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2015年 / 68卷 / 04期

基金：

美国国家科学基金会;

关键词：

Copper(II)-complex; Molecular electro-catalyst; Water reduction; Hydrogen evolution; COBALT; CATALYST; NICKEL; REDUCTION;

D O I：

10.1080/00958972.2014.998657

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of CuCl(2)2H(2)O and a tetradentate amine phenol ligand affords a dinuclear Cu(II) complex, 1, a new molecular electrocatalyst, whose structure has been determined by X-ray crystallography. Electrochemical studies show that 1 can efficiently produce hydrogen from acetic acid with a turnover frequency (TOF) of 50.1 (in DMF) or from water with a TOF of 104.3 (pH7.0) moles of hydrogen per mole of catalyst per hour.

引用

页码：573 / 585

页数：13

共 28 条

[1] STRUCTURES OF N,N'-PROPYLENEBIS[(2-HYDROXY-1-NAPHTHYL)METHANIMINATO]NICKEL(II) AND N,N'-PROPYLENEBIS[(2-HYDROXY-1-NAPHTHYL)METHANIMINATO]COPPER(II)-0.5-DIMETHYL SULFOXIDE [J].

AKHTAR, F ;

DREW, MGB .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (APR) :1149-1154

[2]

Barnett SM, 2012, NAT CHEM, V4, P498, DOI [10.1038/NCHEM.1350, 10.1038/nchem.1350]

[3] A nickel molecular electro-catalyst for generating hydrogen from acetic acid or water [J].

Cao, Jie-Ping ;

Fang, Ting ;

Fu, Ling-Zhi ;

Zhou, Ling-Ling ;

Zhan, Shuzhong .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (21) :10980-10986

[4] Solar Energy Supply and Storage for the Legacy and Non legacy Worlds [J].

Cook, Timothy R. ;

Dogutan, Dilek K. ;

Reece, Steven Y. ;

Surendranath, Yogesh ;

Teets, Thomas S. ;

Nocera, Daniel G. .

CHEMICAL REVIEWS, 2010, 110 (11) :6474-6502

[5] [N,N′-bis(5-bromosalicylidene)-1,3-diaminopropane]nickel(II) and [N,N′-bis(5-chlorosalicylidene)-1,3-diaminopropane]copper(II) [J].

Elmali, A ;

Zeyrek, CT ;

Elerman, Y ;

Svoboda, I .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2000, 56 :1302-1304

[6] ELECTROCATALYTIC REDUCTION OF CARBON-DIOXIDE BY USING MACROCYCLES OF NICKEL AND COBALT [J].

FISHER, B ;

EISENBERG, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (24) :7361-7363

[7] Structure/function relationships of [NiFe]- and [FeFe]-hydrogenases [J].

Fontecilla-Camps, Juan C. ;

Volbeda, Anne ;

Cavazza, Christine ;

Nicolet, Yvain .

CHEMICAL REVIEWS, 2007, 107 (10) :4273-4303

[8] A unique iron-sulfur cluster is crucial for oxygen tolerance of a [NiFe]-hydrogenase [J].

Goris, Tobias ;

Wait, Annemarie F. ;

Saggu, Miguel ;

Fritsch, Johannes ;

Heidary, Nina ;

Stein, Matthias ;

Zebger, Ingo ;

Lendzian, Friedhelm ;

Armstrong, Fraser A. ;

Friedrich, Baerbel ;

Lenz, Oliver .

NATURE CHEMICAL BIOLOGY, 2011, 7 (05) :310-U87

[9] A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production [J].

Helm, Monte L. ;

Stewart, Michael P. ;

Bullock, R. Morris ;

DuBois, M. Rakowski ;

DuBois, Daniel L. .

SCIENCE, 2011, 333 (6044) :863-866

[10] Dinuclear phenoxo-bridged "end-off" complexes containing a piperazine that shows chemical nuclease and cytotoxic activities [J].

Karthick, C. ;

Gurumoorthy, P. ;

Musthafa, M. A. Imran ;

Lakra, Rachita ;

Korrapati, Purna Sai ;

Rahiman, A. Kalilur .

JOURNAL OF COORDINATION CHEMISTRY, 2014, 67 (10) :1794-1808

← 1 2 3 →