2D Nanomaterial-Based Electrocatalyst for Water Soluble Hydroperoxide Reduction

Hydroperoxides generated on lipid peroxidation are highly reactive compounds, tend to form free radicals, and their elevated levels indicate the deterioration of lipid samples. A good alternative to the classical methods for hydroperoxide monitoring are the electroanalytical methods (e.g., a catalytic electrode for their redox-transformation). For this purpose, a series of metal oxides-doped graphitic carbon nitride 2D nanomaterials-have been examined under mild conditions (pH = 7, room temperature) as catalysts for the electrochemical reduction of two water-soluble hydroperoxides: hydrogen peroxide and tert-butyl hydroperoxide. Composition of the electrode modifying phase has been optimized with respect to the catalyst load and binding polymer concentration. The resulting catalytic electrode has been characterized by impedance studies, cyclic voltammetry and chronoamperometry. Electrocatalytic effect of the Co-g-C3N4/Nafion modified electrode on the electrochemical reduction of both hydroperoxides has been proved by comparative studies. An optimal range of operating potentials from -0.215 V to -0.415 V (vs. RHE) was selected with the highest sensitivity achieved at -0.415 V (vs. RHE). At this operating potential, a linear dynamic range from 0.4 to 14 mM has been established by means of constant-potential chronoamperometry with a sensitivity, which is two orders of magnitude higher than that obtained with polymer-covered electrode.