Solvothermal syntheses of Cu3P via reactions of amorphous red phosphorus with a variety of copper sources

被引：35

作者：

Aitken, JA

Ganzha-Hazen, V

Brock, SL ^{[1
]}

机构：

[1] Duquesne Univ, Dept Chem & Biochem, Detroit, MI 48202 USA

[2] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2005年 / 178卷 / 04期

关键词：

solvothermal; hydrothermal; copper phosphide; transition metal phosphide; phosphide; pnictide; low temperature synthesis; microcrystalline;

D O I：

10.1016/j.jssc.2004.10.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Polycrystalline Cu3P was successfully prepared under a wide variety of solvothermal conditions. The reaction of red phosphorus with several copper sources (copper metal, copper (1) iodide, copper (I) chloride and copper (II) chloride) at 150-200 degrees C for 1-2 days in water produced Cu3P. Products were examined with powder X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy. Thermal analyses and optical spectroscopy were also performed. A detailed list of reaction conditions, products and impurity phases (where applicable) are reported. (c) 2004 Elsevier Inc. All rights reserved.

引用

页码：970 / 975

页数：6

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