Spectroscopic Study of the Semihydrate of the Dodecahydro-closo-dodecaborate of 2,4,6-Triamino-1,3,5-triazine

被引：1

作者：

Saldin, V. I. ^{[1
]}

Slobodyuk, A. B. ^{[1
]}

Savchenko, N. N. ^{[1
]}

Ignat'eva, L. N. ^{[1
]}

Buznik, V. M. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Chem, Far Eastern Branch, Vladivostok 690022, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2018年 / 92卷 / 11期

关键词：

IR; NMR B-11; H-1; C; N; semihydrate of 2,4,6-triamino-1,3,5-triazine (melamine) dodecahydro-closo-dodecaborate; directed localized cation-anion interactions; Hartree-Fock method; FEATURES; MELAMINE; SALTS;

D O I：

10.1134/S0036024418110353

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The presence of directed localized cation-anion interactions in the semihydrate of 2,4,6-triamino-1,3,5-triazine (melamine) dodecahydro-closo-dodecaborate (C3H6N6H)(2)B12H12 <bold> </bold>0.5H(2)O is discovered by means of IR and NMR-spectroscopy (B-11, H-1, C, N). The hypothesis that melamine protonation proceeds on the ring atom of nitrogen is confirmed via quantum-chemical calculations.

引用

页码：2210 / 2214

页数：5