Structure, topology and property of metal-organic frameworks with pyridine-3,5-bis(phenyl-4-carboxylate) and varied metal centers

被引：12
作者：
Cui, Pei-Pei [1 ]
Zhang, Xiu-Du [1 ]
Zhao, Yue [1 ]
Chen, Kai [1 ]
Wang, Peng [1 ]
Sun, Wei-Yin [1 ]
机构：
[1] Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Nanjing Natl Lab Microstruct,Sch Chem & Chem Engn, Coordinat Chem Inst,State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
MICROPOROUS AND MESOPOROUS MATERIALS | 2015年 / 208卷
基金：
中国国家自然科学基金;
关键词：
Metal-organic frameworks; Magnetic property; Photoluminescence; Sorption property; COORDINATION POLYMERS; SUPRAMOLECULAR ISOMERISM; SORPTION; LIGAND; HYDROGEN; CONSTRUCTION; FLEXIBILITY; ZINC(II); STORAGE;
D O I：
10.1016/j.micromeso.2015.02.005
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Four new metal-organic frameworks {[Zn(L)]center dot 2.6H(2)O}(n) (1), [Cd(L)(H2O)(DMA)](n) (2), [CO3(L)(2)(HCOO)(2)(H2O)(2)](n) (3) and {[Mn(L)(H2O)]center dot DMF}(n) (4) [H2L = pyridine-3, 5-bis(phenyl-4-carboxylic acid), DMA = N,N-dimethylacetamide, DMF = N,N-dimethylformamide] have been synthesized and characterized by single crystal and powder X-ray diffractions, IR and thermogravimetric analyses. 1 is a threedimensional (3D) framework with {4(6).6(4)} topology, while 2 is a 3D framework formed by parallel/parallel inclined interpenetration of two-dimensional (2D) networks with {6(3)} topology. 3 processes a 3D framework structure with point symbol of {4.8(2)}(2){4(2).8(12).10}, and 4 shows bilayer structure with {4(3).6(3)} topology, which is further assembled into a 3D supramolecular architecture by hydrogen bonding interactions. Gas adsorption property of 1, 2 and 4, photoluminescence of I and 2 as well as magnetic property of 4 were investigated. (C) 2015 Elsevier Inc. All rights reserved.
引用
收藏
页码：188 / 195
页数：8
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