Asymmetric Nanocatalysis: N-Heterocyclic Carbenes as Chiral Modifiers of Fe3O4/Pd nanoparticles

被引：277
作者：
Ranganath, Kalluri V. S. [1 ]
Kloesges, Johannes [1 ]
Schaefer, Andreas H. [2 ]
Glorius, Frank [1 ]
机构：
[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
[2] Nano Analyt GmbH, D-48149 Munster, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 42期
关键词：
alpha-arylation; asymmetric catalysis; chiral modifiers; nanoparticles; N-heterocyclic carbenes; ALPHA-ARYLATION; MAGNETIC NANOPARTICLES; PALLADIUM COMPLEXES; NANOCRYSTALLINE MGO; COUPLING REACTIONS; CATALYSTS; HYDROGENATION; LIGANDS; KETONES; SUZUKI;
D O I：
10.1002/anie.201002782
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Superficial success: A chiral N-heterocyclic carbene (NHC *) is used to modify Fe3O4/Pd nanoparticles, which then catalyze asymmetric α-arylations. This successful synthesis of a heterogeneous catalyst and its appliation in asymmetric catalysis is in stark contrast to the simple immobilization of an established chiral homogeneous catalyst. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：7786 / 7789
页数：4
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