Resonance-Enhanced Multiphoton Ionization Mass Spectrometry (REMPI-MS): Applications for Process Analysis

被引：66
作者：
Streibel, Thorsten [1 ,2 ]
Zimmermann, Ralf [1 ,2 ]
机构：
[1] Univ Rostock, Inst Chem, Joint Mass Spectrometry Ctr, D-18059 Rostock, Germany
[2] German Res Ctr Environm Hlth, Helmholtz Zentrum Munchen, Joint Mass Spectrometry Ctr, D-85764 Neuherberg, Germany
来源：
ANNUAL REVIEW OF ANALYTICAL CHEMISTRY, VOL 7 | 2014年 / 7卷
关键词：
photoionization; time-of-flight mass spectrometry; lasers; combustion; online analysis; exhaust gas; PRESSURE LASER IONIZATION; SINGLE-PHOTON IONIZATION; POLYCYCLIC AROMATIC-HYDROCARBONS; INDIVIDUAL AEROSOL-PARTICLES; INCINERATION PILOT-PLANT; COMPLEX GAS-MIXTURES; REAL-TIME; ONLINE CHARACTERIZATION; 2-PHOTON IONIZATION; SELECTIVE DETECTION;
D O I：
10.1146/annurev-anchem-062012-092648
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Process analysis is an emerging discipline in analytical sciences that poses special requirements on analytical techniques, especially when conducted in an online manner. Mass spectrometric methods seem exceedingly suitable for this task, particularly if a soft ionization method is applied. Resonance-enhanced multiphoton ionization (REMPI) in combination with time-of-flight mass spectrometry (TOFMS) provides a selective and sensitive means for monitoring (poly) aromatic compounds in process flows. The properties of REMPI and various variations of the ionization process are presented. The potential of REMPI for process analysis is highlighted with several examples, and drawbacks of the method are also noted. Applications of REMPI-TOFMS for the detection and monitoring of aromatic species in a large variety of combustion processes comprising flames, vehicle exhaust, and incinerators are discussed. New trends in technical development and combination with other analytical methods are brought forward.
引用
收藏
页码：361 / 381
页数：21
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