Dissolution of Single-Walled Carbon Nanotubes in Alkanol-Cholic Acid Mixtures

被引:13
|
作者
Dyshin, A. A. [1 ]
Eliseeva, O. V. [1 ]
Bondarenko, G. V. [2 ]
Kiselev, M. G. [1 ]
机构
[1] Russian Acad Sci, Krestov Inst Solut Chem, Ivanovo, Russia
[2] Russian Acad Sci, Inst Expt Mineral, Chernogolovka 142432, Moscow Oblast, Russia
基金
俄罗斯基础研究基金会;
关键词
ethanol; propanol; isopropanol; butanol; tert-butanol; cholic acid; single-walled carbon nanotubes; CNT suspensions; dispersion of SWCNTs; solubility of SWCNTs; Raman spectroscopy;
D O I
10.1134/S0036024415090095
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A procedure for dispersing the single-walled carbon nanotubes (SWCNTs) for preparing stable suspensions with high concentrations of individual nanotubes in various alcohols was described. The obtained suspensions were studied by Raman spectroscopy. The solubility of the single-walled carbon nanotubes in alcohols was found to depend on the concentration of cholic acid. The ethanol-surfactant mixture was shown to be the best solvent for all alkanol-cholic acid mixtures (0.018 mol/kg) under study used for preparing time-stable suspensions of single-walled carbon nanotubes. The dissolving ability of aliphatic alcohols was found to decrease in the series: ethanol-isopropanol-tert-butanol-butanol-propanol.
引用
收藏
页码:1628 / 1632
页数:5
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