Authentication of edible vegetable oils adulterated with used frying oil by Fourier Transform Infrared Spectroscopy

被引:140
作者
Zhang, Qing [1 ]
Liu, Cheng [1 ]
Sun, Zhijian [1 ]
Hu, Xiaosong [1 ]
Shen, Qun [1 ]
Wu, Jihong [1 ]
机构
[1] China Agr Univ, Natl Engn & Technol Res Ctr Fruits & Vegetables P, Key Lab Fruits & Vegetables Proc, Minist Agr,Coll Food Sci & Nutr Engn, Beijing 100083, Peoples R China
关键词
Edible vegetable oils; Used frying oil; Adulteration; Fourier Transform Infrared Spectroscopy; Cluster analysis; Discriminant analysis; Linear regression analysis; VIRGIN OLIVE OIL; FATTY-ACID PROFILES; HAZELNUT OIL; CLASSIFICATION; QUALITY;
D O I
10.1016/j.foodchem.2011.11.129
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The application of Fourier Transform Infrared (FTIR) Spectroscopy to authenticate edible vegetable oils (corn, peanut, rapeseed and soybean oil) adulterated with used frying oil was introduced in this paper. The FTIR spectrum of oil was divided into 22 regions which corresponded to the constituents and molecular structures of vegetable oils. Samples of calibration set were classified into four categories for corn and peanut oils and five categories for rapeseed and soybean oils by cluster analysis. Qualitative analysis of validation set was obtained by discriminant analysis. Area ratio between absorption band 19 and 20 and wavenumber shift of band 19 were treated by linear regression for quantitative analysis. For four adulteration types, LODs of area ratio were 6.6%, 7.2%, 5.5%, 3.6% and wavenumber shift were 8.1%, 9.0%, 6.9%, 5.6%, respectively. The proposed methodology is a useful tool to authenticate the edible vegetable oils adulterated with used frying oil. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1607 / 1613
页数:7
相关论文
共 29 条
[11]   Detection of adulteration of extra-virgin olive oil by chemometric analysis of mid-infrared spectral data [J].
Gurdeniz, Gozde ;
Ozen, Banu .
FOOD CHEMISTRY, 2009, 116 (02) :519-525
[12]   Evaluation of the quality of olive oil using fatty acid profiles by direct infusion electrospray ionization mass spectrometry [J].
Lerma-Garcia, M. J. ;
Herrero-Martinez, J. M. ;
Ramis-Ramos, G. ;
Simo-Alfonso, E. F. .
FOOD CHEMISTRY, 2008, 107 (03) :1307-1313
[13]   Rapid evaluation of oxidised fatty acid concentration in virgin olive oil using Fourier-transform infrared spectroscopy and multiple linear regression [J].
Lerma-Garcia, M. J. ;
Simo-Alfonso, E. F. ;
Bendini, A. ;
Cerretani, L. .
FOOD CHEMISTRY, 2011, 124 (02) :679-684
[14]   Discrimination of olive oil adulterated with vegetable oils using dielectric spectroscopy [J].
Lizhi, Hu ;
Toyoda, K. ;
Ihara, I. .
JOURNAL OF FOOD ENGINEERING, 2010, 96 (02) :167-171
[15]   Monitoring of fatty acid composition in virgin olive oil by Fourier transformed infrared spectroscopy coupled with partial least squares [J].
Maggio, Ruben M. ;
Kaufman, Teodoro S. ;
Del Carlo, Michele ;
Cerretani, Lorenzo ;
Bendini, Alessandra ;
Cichelli, Angelo ;
Compagnone, Dario .
FOOD CHEMISTRY, 2009, 114 (04) :1549-1554
[16]   Preliminary studies about thermal degradation of edible oils through attenuated total reflectance mid-infrared spectrometry [J].
Moros, Javier ;
Roth, Meike ;
Garrigues, Salvador ;
de la Guardia, Miguel .
FOOD CHEMISTRY, 2009, 114 (04) :1529-1536
[17]   Detection of hazelnut oil adulteration using FT-IR spectroscopy [J].
Ozen, BF ;
Mauer, LJ .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2002, 50 (14) :3898-3901
[18]   Application of triacylglycerol and fatty acid analyses to discriminate blended sesame oil with soybean oil [J].
Park, Young Woo ;
Chang, Pahn-Shick ;
Lee, JaeHwan .
FOOD CHEMISTRY, 2010, 123 (02) :377-383
[19]   Preliminary studies on the mid-infrared analysis of edible oils by direct heating on an ATR diamond crystal [J].
Pinto, R. Climaco ;
Locquet, N. ;
Eveleigh, L. ;
Rutledge, D. N. .
FOOD CHEMISTRY, 2010, 120 (04) :1170-1177
[20]   Rapid synchronous fluorescence method for virgin olive oil adulteration assessment [J].
Poulli, Konstantina I. ;
Mousdis, George A. ;
Georgiou, Constantinos A. .
FOOD CHEMISTRY, 2007, 105 (01) :369-375