Unusual coordination mode of tetradentate Schiff base cobalt(III) complexes

被引：32
作者：
Cyriac, Anish [1 ]
Jeon, Jong Yeob [1 ]
Varghese, Jobi Kodiyan [1 ]
Park, Ji Hae [1 ]
Choi, Soo Young [2 ]
Chung, Young Keun [2 ]
Lee, Bun Yeoul [1 ]
机构：
[1] Ajou Univ, Dept Mol Sci & Technol, Suwon 443749, South Korea
[2] Seoul Natl Univ, Dept Chem, Seoul 151747, South Korea
来源：
DALTON TRANSACTIONS | 2012年 / 41卷 / 05期
关键词：
CO2/PROPYLENE OXIDE COPOLYMERIZATION; HYDROLYTIC KINETIC RESOLUTION; SALEN COMPLEXES; CARBON-DIOXIDE; ALTERNATING COPOLYMERIZATION; ASYMMETRIC CATALYSIS; CYCLOHEXENE OXIDE; TERMINAL EPOXIDES; EFFICIENT; LIGAND;
D O I：
10.1039/c2dt11871h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Contrary to the stereotype, Jacobsen's catalyst, chiral (salcy)Co(III)OAc adopts an unusual binding mode. The tetradentate {ONNO} ligand does not form a square plane but wraps cobalt in a cis-beta fashion while acetate is chelating.
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收藏
页码：1444 / 1447
页数：4
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