Hypervalent iodine reagents in the total synthesis of natural products

被引：272
|
作者：
Silva, Luiz F., Jr. [1 ]
Olofsson, Berit [2 ]
机构：
[1] Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, BR-05513970 Sao Paulo, Brazil
[2] Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden
来源：
NATURAL PRODUCT REPORTS | 2011年 / 28卷 / 10期
基金：
瑞典研究理事会; 巴西圣保罗研究基金会;
关键词：
O-IODOXYBENZOIC ACID; ENANTIOSELECTIVE TOTAL-SYNTHESIS; SILYL ENOL ETHERS; DIASTEREOSELECTIVE TOTAL-SYNTHESIS; ASYMMETRIC TOTAL-SYNTHESIS; DESS-MARTIN PERIODINANE; CONCISE TOTAL-SYNTHESIS; 1ST TOTAL-SYNTHESIS; AMARYLLIDACEAE ALKALOID (+)-PLICAMINE; CHIRAL DIRHODIUM(II) CARBOXYLATES;
D O I：
10.1039/c1np00028d
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
This report describes the recent applications of hypervalent iodine reagents in the total synthesis of natural products. The large diversity of high-yielding and chemoselective reactions that can be achieved, even for highly functionalized molecules, is summarized, demonstrating that hypervalent iodine reagents have become an essential tool in synthetic organic chemistry.
引用
收藏
页码：1722 / 1754
页数：33
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