Hypervalent iodine reagents in the total synthesis of natural products

被引：272
|
作者：
Silva, Luiz F., Jr. [1 ]
Olofsson, Berit [2 ]
机构：
[1] Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, BR-05513970 Sao Paulo, Brazil
[2] Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden
来源：
NATURAL PRODUCT REPORTS | 2011年 / 28卷 / 10期
基金：
瑞典研究理事会; 巴西圣保罗研究基金会;
关键词：
O-IODOXYBENZOIC ACID; ENANTIOSELECTIVE TOTAL-SYNTHESIS; SILYL ENOL ETHERS; DIASTEREOSELECTIVE TOTAL-SYNTHESIS; ASYMMETRIC TOTAL-SYNTHESIS; DESS-MARTIN PERIODINANE; CONCISE TOTAL-SYNTHESIS; 1ST TOTAL-SYNTHESIS; AMARYLLIDACEAE ALKALOID (+)-PLICAMINE; CHIRAL DIRHODIUM(II) CARBOXYLATES;
D O I：
10.1039/c1np00028d
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
This report describes the recent applications of hypervalent iodine reagents in the total synthesis of natural products. The large diversity of high-yielding and chemoselective reactions that can be achieved, even for highly functionalized molecules, is summarized, demonstrating that hypervalent iodine reagents have become an essential tool in synthetic organic chemistry.
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页码：1722 / 1754
页数：33
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