A Short Way to Switchable Carbenes

被引:117
作者
Hashmi, A. Stephen K. [1 ]
Lothschuetz, Christian [1 ]
Graf, Katharina [1 ]
Haeffner, Tobias [1 ]
Schuster, Andreas [1 ]
Rominger, Frank [1 ]
机构
[1] Heidelberg Univ, Inst Organ Chem, D-69120 Heidelberg, Germany
关键词
carbene ligands; gold; isonitriles; palladium; platinum; vinylgold species; GOLD CATALYSIS; HETEROCYCLIC CARBENES; TEMPLATE SYNTHESIS; COMPLEXES; PALLADIUM; PLATINUM; LIGANDS; ISOCYANIDE; MECHANISM;
D O I
10.1002/adsc.201100183
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A new, one-step route to N-heterocyclic oxo-carbene complexes (NHOCs), representatives of chemo-switchable NHC complexes, is reported. This simple procedure provides an easy access to gold, palladium and platinum complexes of these ligands.
引用
收藏
页码:1407 / 1412
页数:6
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