A Short Way to Switchable Carbenes

被引：117

作者：

Hashmi, A. Stephen K. ^{[1
]}

Lothschuetz, Christian ^{[1
]}

Graf, Katharina ^{[1
]}

Haeffner, Tobias ^{[1
]}

Schuster, Andreas ^{[1
]}

Rominger, Frank ^{[1
]}

机构：

[1] Heidelberg Univ, Inst Organ Chem, D-69120 Heidelberg, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2011年 / 353卷 / 09期

关键词：

carbene ligands; gold; isonitriles; palladium; platinum; vinylgold species; GOLD CATALYSIS; HETEROCYCLIC CARBENES; TEMPLATE SYNTHESIS; COMPLEXES; PALLADIUM; PLATINUM; LIGANDS; ISOCYANIDE; MECHANISM;

D O I：

10.1002/adsc.201100183

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A new, one-step route to N-heterocyclic oxo-carbene complexes (NHOCs), representatives of chemo-switchable NHC complexes, is reported. This simple procedure provides an easy access to gold, palladium and platinum complexes of these ligands.

引用

页码：1407 / 1412

页数：6

共 31 条

[1]

[Anonymous], 2004, ANGEW CHEM, DOI DOI 10.1002/ANGE.200460232

[2]

[Anonymous], 2010, ANGEW CHEM INT EDIT

[3] PLATINUM AND PALLADIUM COMPLEXES FORMED BY CHELATIVE ADDITION OF AMINES TO ISOCYANIDES [J].

BALCH, AL ;

PARKS, JE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (13) :4114-4121

[4] Facile Derivatization of a "Chemo-active" NHC Incorporating an Enolate Backbone and Relevant Tuning of Its Electronic Properties [J].

Benhamou, Laure ;

Vujkovic, Nadia ;

Cesar, Vincent ;

Gornitzka, Heinz ;

Lugan, Noel ;

Lavigne, Guy .

ORGANOMETALLICS, 2010, 29 (11) :2616-2630

[5] Imidazol-2-ylidene-4-olate: an anionic N-heterocyclic carbene pre-programmed for further derivatization [J].

Benhamou, Laure ;

Cesar, Vincent ;

Gornitzka, Heinz ;

Lugan, Noel ;

Lavigne, Guy .

CHEMICAL COMMUNICATIONS, 2009, (31) :4720-4722

[6] PALLADIUM AND PLATINUM COMPLEXES RESULTING FROM ADDITION OF HYDRAZINE TO COORDINATED ISOCYANIDE [J].

BURKE, A ;

BALCH, AL ;

ENEMARK, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (08) :2555-+

[7] Electronic Tuning of a Carbene Center via Remote Chemical Induction, and Relevant Effects in Catalysis [J].

Cesar, Vincent ;

Lugan, Noel ;

Lavigne, Guy .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (37) :11432-11442

[8] The Measure of All Rings-N-Heterocyclic Carbenes [J].

Droege, Thomas ;

Glorius, Frank .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (39) :6940-6952

[9]

Hahn F.E., 2008, Angew. Chem., V120, P3166

[10] Heterocyclic carbenes: Synthesis and coordination chemistry [J].

Hahn, F. Ekkehardt ;

Jahnke, Mareike C. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (17) :3122-3172

← 1 2 3 4 →