Rational control of the interlayer space inside two-dimensional titanium carbides for highly efficient uranium removal and imprisonment

被引：223
作者：
Wang, Lin [1 ,2 ]
Tao, Wuqing [1 ,2 ,3 ]
Yuan, Liyong [1 ,2 ]
Liu, Zhirong [3 ]
Huang, Qing [4 ]
Chai, Zhifang [1 ,2 ]
Gibson, John K. [5 ]
Shi, Weiqun [1 ,2 ]
机构：
[1] Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China
[2] Chinese Acad Sci, Inst High Energy Phys, Key Lab Biomed Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China
[3] East China Univ Technol, Sch Chem Biol & Mat Sci, Nanchang 330013, Jiangxi, Peoples R China
[4] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China
[5] LBNL, Chem Sci Div, Berkeley, CA 94720 USA
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 89期
关键词：
HIGH VOLUMETRIC CAPACITANCE; MXENE; ADSORPTION; GRAPHENE; WATER; INTERCALATION; URANYL; LAYERS; TI3C2; FILMS;
D O I：
10.1039/c7cc06740b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Though two-dimensional early transition metal carbides and carbonitrides (MXenes) have attracted extensive interest recently, their superb abilities in various scientific applications always suffer from the very narrow interlayer space inside the multilayered structure. Here we demonstrate an unprecedented large adsorption capacity enhancement of Ti(3)C(2)Tx toward radionuclide removal via a hydrated intercalation strategy. By rational control of the interlayer space, the potential for imprisoning the representative actinide U(VI) inside multilayered Ti(3)C(2)Tx was also confirmed.
引用
收藏
页码：12084 / 12087
页数：4
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