A short ride on scorpionates: from d- to f-elements

被引:45
|
作者
Paulo, A [1 ]
Correia, JDG [1 ]
Campello, MPC [1 ]
Santos, I [1 ]
机构
[1] Inst Tecnol & Nucl, Dept Quim, P-2686953 Sacavem, Portugal
关键词
scorpionate ligands; technetium; rhenium; uranium;
D O I
10.1016/j.poly.2003.11.022
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This paper presents an over-view of progress involving group 7 elements and actinides with scorpionate ligands. This includes oxides, polyhydrides and carbonyls of group 7 elements and any type of compounds of actinides (III) and (IV). Synthetic procedures, reactivity and structural data are reviewed. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:331 / 360
页数:30
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