Synthesis of 4H/fcc-Au@M (M = Ir, Os, IrOs) Core-Shell Nanoribbons For Electrocatalytic Oxygen Evolution Reaction

被引:62
作者
Fan, Zhanxi [1 ]
Luo, Zhimin [1 ]
Chen, Ye [1 ]
Wang, Jie [1 ]
Li, Bing [2 ]
Zong, Yun [2 ]
Zhang, Hua [1 ]
机构
[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Ctr Programmable Mat, 50 Nanyang Ave, Singapore 639798, Singapore
[2] ASTAR, Inst Mat Res & Engn, 2 Fusionopolis Way,Innovis 08-03, Singapore 138634, Singapore
关键词
FUEL-CELL CATALYSTS; METAL NANOCRYSTALS; AT-PT; REDUCTION REACTION; EPITAXIAL-GROWTH; SQUARE SHEETS; NANOPARTICLES; SURFACE; STRAIN; PHASE;
D O I
10.1002/smll.201601787
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The high-yield synthesis of 4H/face-centered cubic (fcc)-Au@Ir core-shell nanoribbons (NRBs) is achieved via the direct growth of Ir on 4H Au NRBs under ambient conditions. Importantly, this method can be used to synthesize 4H/fcc-Au@Os and 4H/fcc-Au@IrOs core-shell NRBs. Significantly, the obtained 4H/fcc-Au@Ir core-shell NRBs demonstrate an exceptional electrocatalytic activity toward the oxygen evolution reaction under acidic condition, which is much higher than that of the commercial Ir/C catalyst.
引用
收藏
页码:3908 / 3913
页数:6
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