Nickel(II) and copper(II) complexes with an asymmetric bidentate Schiff-base ligand derived from furfurylamine

被引：39
|
作者：
Khalaji, Aliakbar Dehno [1 ]
Rad, Sepideh Maghsodlou [1 ]
Grivani, Gholamhossein [2 ]
Das, Debasis [3 ]
机构：
[1] Golestan Univ, Fac Sci, Dept Chem, Gorgan, Iran
[2] Damghan Univ, Sch Chem, Damghan, Iran
[3] Univ Burdwan, Dept Chem, Burdwan 713104, W Bengal, India
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2011年 / 103卷 / 02期
关键词：
Schiff-base; Nickel(II); Copper(II); Spectroscopy; Thermogravimetry; THERMAL-DECOMPOSITION; CRYSTAL-STRUCTURES; MAGNETIC-PROPERTIES; ZINC(II) COMPLEXES;
D O I：
10.1007/s10973-010-1024-1
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
New asymmetric bidentate Schiff-base ligand (5-bromo-2-hydroxybenzyl-2-furylmethyl)imine, (HL), and its nickel(II) and copper(II) complexes with the general composition ML2 [M = Ni (1) and Cu (2)], were prepared. The ligand and the metal complexes were characterized by elemental analysis, FT-IR, and UV-Vis spectroscopy. In addition, H-1-NMR and X-ray powder diffraction (XRD) were employed for characterization of ligand and metal complexes, respectively. Thermogravimetric analysis (TGA) of the ligand and metal complexes revealed the thermal stability and decomposition pattern of the species.
引用
收藏
页码：747 / 751
页数：5
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