Bimetallic nickel-iridium nanocatalysts for hydrogen generation by decomposition of hydrous hydrazine

被引:187
作者
Singh, Sanjay Kumar [1 ]
Xu, Qiang [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Osaka, Japan
关键词
CATALYTIC DECOMPOSITION; ROOM-TEMPERATURE; AMMONIA-BORANE; STORAGE; NANOPARTICLES; REDUCTION; HYDRATE; OXYGEN;
D O I
10.1039/c0cc01879a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Alloying Ni with Ir leads to the formation of highly active catalysts for complete decomposition of hydrous hydrazine with 100% H(2) selectivity at room temperature. Use of surfactants enhances the activity by suppressing the agglomeration of nanoparticles, but does not affect the bimetallic compositions of the nanoparticles.
引用
收藏
页码:6545 / 6547
页数:3
相关论文
共 22 条
[1]  
Armstrong W.E., 1978, US Patent, Patent No. [4 124 538, 4124538]
[2]   A high-performance hydrogen generation system: Transition metal-catalyzed dissociation and hydrolysis of ammonia-borane [J].
Chandra, Manish ;
Xu, Qiang .
JOURNAL OF POWER SOURCES, 2006, 156 (02) :190-194
[3]   The reaction route and active site of catalytic decomposition of hydrazine over molybdenum nitride catalyst [J].
Chen, XW ;
Zhang, T ;
Zheng, MY ;
Wu, ZL ;
Wu, WC ;
Li, C .
JOURNAL OF CATALYSIS, 2004, 224 (02) :473-478
[4]   Characterization of iridium catalyst for decomposition of hydrazine hydrate for hydrogen generation [J].
Cho, Sung June ;
Lee, Jun ;
Lee, Yun Sung ;
Kim, Dong Pyo .
CATALYSIS LETTERS, 2006, 109 (3-4) :181-187
[5]   Nanoalloys: From theory to applications of alloy clusters and nanoparticles [J].
Ferrando, Riccardo ;
Jellinek, Julius ;
Johnston, Roy L. .
CHEMICAL REVIEWS, 2008, 108 (03) :845-910
[6]   B-N compounds for chemical hydrogen storage [J].
Hamilton, Charles W. ;
Baker, R. Tom ;
Staubitz, Anne ;
Manners, Ian .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) :279-293
[7]   Preparation of iridium catalyst and its catalytic activity over hydrazine hydrate decomposition for hydrogen production and storage [J].
Jang, Young Bae ;
Kim, Tak Hee ;
Sun, Min Ho ;
Lee, Jun ;
Cho, Sung June .
CATALYSIS TODAY, 2009, 146 (1-2) :196-201
[8]  
Ji XL, 2010, NAT CHEM, V2, P286, DOI [10.1038/NCHEM.553, 10.1038/nchem.553]
[9]   Liquid-Phase Chemical Hydrogen Storage: Catalytic Hydrogen Generation under Ambient Conditions [J].
Jiang, Hai-Long ;
Singh, Sanjay Kumar ;
Yan, Jun-Min ;
Zhang, Xin-Bo ;
Xu, Qiang .
CHEMSUSCHEM, 2010, 3 (05) :541-549
[10]   Structurally Ordered FePt Nanoparticles and Their Enhanced Catalysis for Oxygen Reduction Reaction [J].
Kim, Jaemin ;
Lee, Youngmin ;
Sun, Shouheng .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (14) :4996-+