The electrochemical discharges for the synthesis of nickel oxide nanoparticles: Characterization and mechanism

被引：28

作者：

Allagui, Anis ^{[1
]}

Wuethrich, Rolf ^{[1
]}

机构：

[1] Concordia Univ, Dept Mech & Ind Engn, Montreal, PQ H3G 1M8, Canada

来源：

ELECTROCHIMICA ACTA | 2011年 / 58卷

基金：

加拿大自然科学与工程研究理事会;

关键词：

Nanoparticles; Electrochemical discharges; Plasma electrolysis; Radiation chemistry; SONOCHEMICAL SYNTHESIS; CATALYTIC-PROPERTIES; METAL NANOPARTICLES; OPTICAL-PROPERTIES; PARTICLES; SIZE; GOLD; COLLOIDS; CLUSTERS; TEMPERATURE;

D O I：

10.1016/j.electacta.2011.08.040

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Electrochemical discharges in aqueous solution of sulphuric acid and ethanol as scavenger of hydroxyl radicals, in addition to polyvinylpyrrolidone as stabilizing agent are used for the synthesis of nano-sized nickel oxide colloids. Morphological characterization by electron microscopy and powder X-ray diffraction has been performed to examine the obtained particles at different terminal voltages and experiment durations. From the qualitative resemblance of the electrochemical discharges to the radiolysis technique, a microscopic mechanistic model is proposed giving an overall picture of the physicochemical phenomenon for the synthesis of fine particles. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：12 / 18

页数：7

共 58 条

[1] Less is more in medicine - Sophisticated forms of nanotechnology will find some of their first real-world applications in biomedical research, disease diagnosis and, possibly, therapy [J].

Alivisatos, AP .

SCIENTIFIC AMERICAN, 2001, 285 (03) :66-73

[2]

Allagui A., 2008, MICR NAN RES C IEEE, V1, P65, DOI DOI 10.1109/MNRC.2008.4683379

[3] Gas film formation time and gas film life time during electrochemical discharge phenomenon [J].

Allagui, Anis ;

Wuethrich, Rolf .

ELECTROCHIMICA ACTA, 2009, 54 (23) :5336-5343

[4] Efficient Synthesis of Gold Nanoparticles Using Ion Irradiation in Gas-Liquid Interfacial Plasmas [J].

Baba, Kazuhiko ;

Kaneko, Toshiro ;

Hatakeyama, Rikizo .

APPLIED PHYSICS EXPRESS, 2009, 2 (03)

[5] Magnetic and structural properties of isolated and assembled clusters [J].

Bansmann, J ;

Baker, SH ;

Binns, C ;

Blackman, JA ;

Bucher, JP ;

Dorantes-Dávila, J ;

Dupuis, V ;

Favre, L ;

Kechrakos, D ;

Kleibert, A ;

Meiwes-Broer, KH ;

Pastor, GM ;

Perez, A ;

Toulemonde, O ;

Trohidou, KN ;

Tuaillon, J ;

Xie, Y .

SURFACE SCIENCE REPORTS, 2005, 56 (6-7) :189-275

[6] The impact of nanoscience on heterogeneous catalysis [J].

Bell, AT .

SCIENCE, 2003, 299 (5613) :1688-1691

[7] THE PREPARATION OF MONODISPERSE COLLOIDAL METAL PARTICLES FROM MICRO-EMULSIONS [J].

BOUTONNET, M ;

KIZLING, J ;

STENIUS, P .

COLLOIDS AND SURFACES, 1982, 5 (03) :209-225

[8] SIZE EFFECT ON MELTING TEMPERATURE OF GOLD PARTICLES [J].

BUFFAT, P ;

BOREL, JP .

PHYSICAL REVIEW A, 1976, 13 (06) :2287-2298

[9] Synthesis of ultra-small ZnS nanoparticles by solid-solid reaction in the confined space of AOT reversed micelles [J].

Calandra, P ;

Longo, A ;

Liveri, VT .

JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (01) :25-30

[10]

Chang F.-C., 2010, J VACUUM SCI TECHN A, V28

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