Kinetics of electrochemical lithium intercalation into thin tungsten (VI) oxide layers

被引：39

作者：

Churikov, A. V. ^{[1
]}

Ivanishchev, A. V. ^{[1
]}

Ivanishcheva, I. A. ^{[1
]}

Zapsis, K. V. ^{[1
]}

Gamayunova, I. M. ^{[1
]}

Sycheva, V. O. ^{[1
]}

机构：

[1] Chernyshevsky Saratov State Univ, Saratov 410012, Russia

来源：

RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2008年 / 44卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

intercalation; lithium; tungsten oxide; chronopotentiometry; voltammetry; impedance spectroscopy; diffusion;

D O I：

10.1134/S1023193508050054

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The methods of galvanostatic intermittent titration, cyclic voltammetry, and electrode impedance spectroscopy are used to study the behavior of tungsten (VI) oxide film electrodes free of binding and conducting additives in the course of reversible lithium intercalation from nonaqueous electrolyte at 25 degrees C. The studies are performed for electrodes with different degrees of crystallinity at the variation of the lithium concentration in intercalate from zero to 0.017 mol/cm(3). Lithium diffusion coefficient is in the range of 10(-11)-10(-16) cm(2)/s. The concentration dependences of the intercalation-layer transport parameters are analyzed, the equivalent circuit versions are discussed, and results obtained by different methods are compared.

引用

页码：530 / 542

页数：13

共 44 条

[1] ALESHINA LA, 1998, ELEKTROKHIMIYA, V34, P988
[2] ELECTROCHROMISM IN NIOX AND WOX OBTAINED BY SPRAY-PYROLYSIS
ARAKAKI, J
REYES, R
HORN, M
ESTRADA, W
[J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1995, 37 (01) : 33 - 41
[3] Intercalation inWO3 and WO3:Li films
Avellaneda, CO
Bulhoes, LOS
[J]. SOLID STATE IONICS, 2003, 165 (1-4) : 59 - 64
[4] Deposition of non-stoichiometric tungsten oxides plus MO2 composites (M = Ru or Ir) and study of their catalytic properties in hydrogen or oxygen evolution reactions
Baruffaldi, C
Cattarin, S
Musiani, M
[J]. ELECTROCHIMICA ACTA, 2003, 48 (25-26) : 3921 - 3927
[5] A study of thin anodic WO3 films by electrochemical impedance spectroscopy
Biaggio, SR
Rocha-Filho, RC
Vilche, JR
Varela, FE
Gassa, LM
[J]. ELECTROCHIMICA ACTA, 1997, 42 (11) : 1751 - 1758
[6] AN ELECTROCHEMICAL QUARTZ-CRYSTAL MICROBALANCE STUDY OF LITHIUM INSERTION INTO THIN-FILMS OF TUNGSTEN TRIOXIDE .2. EXPERIMENTAL RESULTS AND COMPARISON WITH MODEL-CALCULATIONS
BOHNKE, O
VUILLEMIN, B
GABRIELLI, C
KEDDAM, M
PERROT, H
[J]. ELECTROCHIMICA ACTA, 1995, 40 (17) : 2765 - 2773
[7] NO2 sensitivity of WO3 thin film obtained by high vacuum thermal evaporation
Cantalini, C
Sun, HT
Faccio, M
Pelino, M
Santucci, S
Lozzi, L
Passacantando, M
[J]. SENSORS AND ACTUATORS B-CHEMICAL, 1996, 31 (1-2) : 81 - 87
[8] CHOI YM, 1995, J POWER SOURCES, V56, P25, DOI 10.1016/0378-7753(95)80004-Z
[9] Effects of cation mixing on the electrochemical lithium intercalation reaction into porous Li1-delta Ni1-yCoyO2 electrodes
Choi, YM
Pyun, SI
Moon, SI
[J]. SOLID STATE IONICS, 1996, 89 (1-2) : 43 - 52
[10] Churikov A.V., 2003, ELEKTROKHIM ENERGETI, V3, P124

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