Qualitative By-Product Identification of Plasma-Assisted TCE Abatement by Mass Spectrometry and Fourier-Transform Infrared Spectroscopy

被引：18

作者：

Vandenbroucke, Arne M. ^{[1
]}

Minh Tuan Nguyen Dinh ^{[2
]}

Giraudon, Jean-Marc ^{[2
]}

Morent, Rino ^{[1
]}

De Geyter, Nathalie ^{[1
]}

Lamonier, Jean-Francois ^{[2
]}

Leys, Christophe ^{[1
]}

机构：

[1] Univ Ghent, Dept Appl Phys, Res Unit Plasma Technol, B-9000 Ghent, Belgium

[2] Univ Sci & Technol Lille, Unite Catalyse & Chim Solide UMR CNRS 8181, F-59655 Villeneuve Dascq, France

来源：

PLASMA CHEMISTRY AND PLASMA PROCESSING | 2011年 / 31卷 / 05期

关键词：

Non-thermal plasma; VOC; Negative DC glow discharge; By-products; FT-IR; MS; VOLATILE ORGANIC-COMPOUNDS; AIR-POLLUTION CONTROL; WASTE-GAS TREATMENT; NONTHERMAL PLASMA; ELECTRICAL-DISCHARGE; ATMOSPHERIC-PRESSURE; CATALYTIC COMBUSTION; GLOW-DISCHARGE; DECOMPOSITION; REMOVAL;

D O I：

10.1007/s11090-011-9310-7

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

In this study, the formation of by-products resulting from the decomposition of trichloroethylene with a negative DC glow discharge has been investigated. By combining the qualitative data from mass spectrometry and Fourier-transform infrared spectroscopy, the formation of phosgene, dichloroacetylchloride and trichloroacetaldehyde have been confirmed as incomplete oxidation products. Hydrogen chloride, chlorine, carbon monoxide and carbon dioxide were also detected. Also, formation of ozone was found in the outlet stream. Based on this information, it is possible to chose an appropriate catalyst to combine with non thermal plasma. In this way emission of harmful, incomplete oxidation products can be further reduced at a lower energy cost.

引用

页码：707 / 718

页数：12

共 37 条

[1] The influence of electrode geometry and gas flow on corona-to-glow and glow-to-spark threshold currents in air [J].

Akishev, Y ;

Goossens, O ;

Callebaut, T ;

Leys, C ;

Napartovich, A ;

Trushkin, N .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2001, 34 (18) :2875-2882

[2] DC GLOW-DISCHARGE IN AIR-FLOW AT ATMOSPHERIC-PRESSURE IN CONNECTION WITH WASTE GASES TREATMENT [J].

AKISHEV, YS ;

DERYUGIN, AA ;

KOCHETOV, IV ;

NAPARTOVICH, AP ;

TRUSHKIN, NI .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1993, 26 (10) :1630-1637

[3] Atmospheric chemistry of VOCs and NOx [J].

Atkinson, R .

ATMOSPHERIC ENVIRONMENT, 2000, 34 (12-14) :2063-2101

[4] Electrical discharge regimes and aerosol production in point-to-plane dc high-pressure cold plasmas: Aerosol production by electrical discharges [J].

Borra, JP ;

Goldman, A ;

Goldman, M ;

Boulaud, D .

JOURNAL OF AEROSOL SCIENCE, 1998, 29 (5-6) :661-674

[5] Removal of gaseous toluene and submicron aerosol particles using a dielectric barrier discharge reactor [J].

Byeon, Jeong Hoon ;

Park, Jae Hong ;

Jo, Yoon Shin ;

Yoon, Ki Young ;

Hwang, Jungho .

JOURNAL OF HAZARDOUS MATERIALS, 2010, 175 (1-3) :417-422

[6] Removal of Volatile Organic Compounds by Single-Stage and Two-Stage Plasma Catalysis Systems: A Review of the Performance Enhancement Mechanisms, Current Status, and Suitable Applications [J].

Chen, Hsin Liang ;

Lee, How Ming ;

Chen, Shiaw Huei ;

Chang, Moo Been ;

Yu, Sheng Jen ;

Li, Shou Nan .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2009, 43 (07) :2216-2227

[7]

Degrève J, 2001, FILTR SEPARAT, V38, P49

[8] OZONE SYNTHESIS FROM OXYGEN IN DIELECTRIC BARRIER DISCHARGES [J].

ELIASSON, B ;

HIRTH, M ;

KOGELSCHATZ, U .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1987, 20 (11) :1421-1437

[9] PLASMA REMEDIATION OF TRICHLOROETHYLENE IN SILENT DISCHARGE PLASMAS [J].

EVANS, D ;

ROSOCHA, LA ;

ANDERSON, GK ;

COOGAN, JJ ;

KUSHNER, MJ .

JOURNAL OF APPLIED PHYSICS, 1993, 74 (09) :5378-5386

[10] Catalytic combustion of volatile organic compounds [J].

Everaert, K ;

Baeyens, J .

JOURNAL OF HAZARDOUS MATERIALS, 2004, 109 (1-3) :113-139

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