[(E)-N′-(5-Chloro-2-oxidobenzylideneκO)-3,4,5-trimethoxybenzohydrazidato-κ2N′,O](pyridine-κN)copper(II)

被引：0

作者：

Wang, Yu-Min ^{[1
]}

Lin, Xiao-Hui ^{[1
]}

Chen, Zhen ^{[1
]}

Jiang, Hong-Li ^{[1
]}

Zhang, Chang-Jun ^{[1
]}

机构：

[1] Taishan Med Univ, Sch Chem & Chem Engn, Tai An 271016, Shandong, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

COPPER(II); COMPLEXES;

D O I：

10.1107/S1600536811009901

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Cu(C17H15ClN2O5)(C5H5N)], the Cu-II atom is coordinated by one N atom and two O atoms from an anionic salicylaldehyde benzoylhydrazone ligand and one pyridine N atom in a distorted square-planar geometry. The bonds displays the usual elongation with mean Cu-O and Cu-N bond lengths of 1.926 and 1.976 angstrom, respectively. The pyridine ring makes dihedral angles of 26.12 (13) and 11.08 (12)degrees, respectively, with the trimethoxyphenyl and phenolate rings, which make a dihedral angle of 16.05 (12)degrees with one another.

引用

页码：M526 / U248

页数：11

共 6 条

[1]

Bruker, 1998, SMART SAINT SADABS

[2] COPPER(II) COMPLEXES OF THE ANTITUMOR-RELATED LIGAND SALICYLALDEHYDE ACETYLHYDRAZONE (H(2)L) AND THE SINGLE-CRYSTAL X-RAY STRUCTURES OF [(CU(HL)H2O)(2)]CENTER-DOT-2(NO3) AND [(CU(HL)(PYRIDINE)(NO3))(2)] [J].

CHAN, SC ;

KOH, LL ;

LEUNG, PH ;

RANFORD, JD ;

SIM, KY .

INORGANICA CHIMICA ACTA, 1995, 236 (1-2) :101-108

[3] Synthesis, characterization and physicochemical properties of copper(II) complexes containing salicylaldehyde semicarbazone [J].

Lee, PF ;

Yang, CT ;

Fan, DM ;

Vittal, JJ ;

Ranford, JD .

POLYHEDRON, 2003, 22 (20) :2781-2786

[4] Structure and magnetic properties of a tetranuclear Cu4O4 open-cubane in [Cu(L)]4•4H2O with L2- = (E)-N′-(2-oxy-3-methoxybenzylidene)benzohydrazide [J].

Monfared, Hassan Hosseini ;

Sanchiz, Joaquin ;

Kalantari, Zahra ;

Janiak, Christoph .

INORGANICA CHIMICA ACTA, 2009, 362 (10) :3791-3795

[5] Dicopper(II) complexes of the antitumor analogues acylbis(salicylaldehyde hydrazones) and crystal structures of monomeric [Cu2(1,3-propanedioyl bis(salicylaldehyde hydrazone))(H2O)2]•(ClO4)2•3H2O and polymeric [{Cu2(1,6-hexanedioyl bis(salicylaldehyde hydrazone))(C2H5OH)2}m]•(ClO4)2m•m(C2H5OH) [J].

Ranford, JD ;

Vittal, JJ ;

Wang, YM .

INORGANIC CHEMISTRY, 1998, 37 (06) :1226-1231

[6] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

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