Corrosion protection of 316 L stainless steel by a TiO2 nanoparticle coating prepared by sol-gel method

被引：294

作者：

Shen, GX ^{[1
]}

Chen, YC ^{[1
]}

Lin, CJ ^{[1
]}

机构：

[1] Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China

来源：

THIN SOLID FILMS | 2005年 / 489卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

TiO2 nanoparticle coatings; 316 L stainless steel; corrosion protection; photoelectrochemical performance;

D O I：

10.1016/j.tsf.2005.05.016

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A uniform and TiO2 nanoparticle coating on steels has been prepared using sol-gel method and hydrothermal post-treatments. The morphology and structure of the coatings were analysed using atomic force microscopy and X-ray diffraction. The anticorrosion performances of the coatings in dark and under ultraviolet illumination have been evaluated by using electrochemical techniques. The influences of coating thickness, pH and NaCl concentration on corrosion protection have been examined as well. The results indicate that the TiO2 nanoparticle coatings on steels exhibit an excellent corrosion resistance due to a ceramic protective barrier on metal surface in dark, and a photo-generated cathodic protection current under UV illumination. The electrochemical impedance spectroscopy measurements provide an explanation to the increased resistance of nano TiO2 particles coated 316 L stainless steel against corTosion. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：130 / 136

页数：7

共 18 条

[1] A NONLINEAR LEAST-SQUARES FIT PROCEDURE FOR ANALYSIS OF IMMITTANCE DATA OF ELECTROCHEMICAL SYSTEMS [J].

BOUKAMP, BA .

SOLID STATE IONICS, 1986, 20 (01) :31-44

[2] Corrosion-resistant coatings:: a nanotechnology approach [J].

Carbajal, G ;

Martínez-Villafañe, A ;

Gonzalez-Rodriguez, JG ;

Castaño, VM .

ANTI-CORROSION METHODS AND MATERIALS, 2001, 48 (04) :241-244

[3] ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].

FUJISHIMA, A ;

HONDA, K .

NATURE, 1972, 238 (5358) :37-+

[4] GALVANIC COUPLES OF 316L STEEL WITH TI AND ION PLATED TI AND TIN COATINGS IN RINGERS SOLUTIONS [J].

GLUSZEK, J ;

JEDRKOWIAK, J ;

MARKOWSKI, J ;

MASALSKI, J .

BIOMATERIALS, 1990, 11 (05) :330-335

[5] Influence of the mixed ratio on the photocurrent of the TiO2/SnO2 composite photoelectrodes sensitized by mercurochrome [J].

Liu, ZY ;

Pan, K ;

Wang, MJ ;

Liu, M ;

Lü, Q ;

Bai, YB ;

Li, TJ .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2003, 157 (01) :39-46

[6] Improvement in corrosion resistance of the 3161 stainless steel by means of Al2O3 coatings deposited by the sol-gel method [J].

Masalski, J ;

Gluszek, J ;

Zabrzeski, J ;

Nitsch, K ;

Gluszek, P .

THIN SOLID FILMS, 1999, 349 (1-2) :186-190

[7] Corrosion and leaching of silver doped ceramic IBAD coatings on SS 316L under simulated physiological conditions [J].

Meinert, K ;

Uerpmann, C ;

Matschullat, J ;

Wolf, GK .

SURFACE & COATINGS TECHNOLOGY, 1998, 104 :58-65

[8] Photoelectrochemical anticorrosion and self-cleaning effects of a TiO2 coating for type 304 stainless steel [J].

Ohko, Y ;

Saitoh, S ;

Tatsuma, T ;

Fujishima, A .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (01) :B24-B28

[9] Photoelectrochemical approach for metal corrosion prevention using a semiconductor photoanode [J].

Park, H ;

Kim, KY ;

Choi, W .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (18) :4775-4781

[10] A novel photoelectrochemical method of metal corrosion prevention using a TiO2 solar panel [J].

Park, H ;

Kim, KY ;

Choi, W .

CHEMICAL COMMUNICATIONS, 2001, (03) :281-282

← 1 2 →