Effect of segmented fluid flow, sonication and phase transfer catalysis on biphasic reactions in capillary microreactors

被引：70

作者：

Ahmed-Omer, Batoul ^{[1
,2
]}

Barrow, David ^{[1
]}

Wirth, Thomas ^{[2
]}

机构：

[1] Cardiff Univ, Cardiff Sch Engn, Lab Appl Microsyst, Cardiff CF24 3TF, S Glam, Wales

[2] Cardiff Univ, Cardiff Sch Chem, Cardiff CF10 3AT, S Glam, Wales

来源：

CHEMICAL ENGINEERING JOURNAL | 2008年 / 135卷 / S280-S283期

关键词：

microreactors; phase transfer catalysis; segmented flow; sonochemistry;

D O I：

10.1016/j.cej.2007.07.017

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The contact between immiscible liquids in a microfluidic system creating segmented flow offers great potential in the study of biphasic reactions in organic chemistry with significant advantages with respect to conventional flask techniques. For a simple biphasic hydrolysis, we show that the application of various reaction conditions in microreactors using segmented flow can dramatically increase the reaction rate, especially when sonication and phase transfer catalysis are combined with segmentation. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：S280 / S283

页数：4

共 34 条

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