Synthesis of a novel graphene conjugated covalent organic framework nanohybrid for enhancing the flame retardancy and mechanical properties of epoxy resins through synergistic effect

被引：130

作者：

Xiao, Yuling ^{[1
]}

Jin, Ziyu ^{[1
]}

He, Lingxin ^{[1
]}

Ma, Shicong ^{[1
]}

Wang, Chenyu ^{[1
]}

Mu, Xiaowei ^{[1
]}

Song, Lei ^{[1
]}

机构：

[1] Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Peoples R China

来源：

COMPOSITES PART B-ENGINEERING | 2020年 / 182卷

基金：

中国国家自然科学基金;

关键词：

Graphene conjugated covalent organic framework; Synergistic effect; Epoxy resin; Flame retardant; Mechanical performances; MOLYBDENUM-DISULFIDE NANOSHEETS; THERMAL-STABILITY; POLYMER NETWORKS; FIRE HAZARDS; HYBRID; OXIDE; CO; SUPPRESSION; PERFORMANCE; COMPOSITE;

D O I：

10.1016/j.compositesb.2019.107616

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A novel graphene conjugated covalent organic framework (AGO@COF) nanohybrid was synthesized by solvothermal method and used to enhance the flame retardancy and mechanical performances of epoxy resins (EP) through synergistic effect firstly. It is deduced from thermogravimetric analysis and cone calorimeter results that the obtained AGO@COF nanohybrid improves the flame retardancy of EP significantly. The time to peak heat release rate of EP increases by 17 s, the peak heat release rate and total heat release of EP decrease by 43.6 and 24.3% due to incorporation of 2 wt% AGO@COF. It is referred from thermogravimetric analysis-fourier transform infrared spectrometry results that the release of toxic gases and combustible volatiles during pyrolysis is also suppressed. As for mechanical performance of EP nanocomposites, the storage modulus of EP/2 wt% AGO@COF (34.66 GPa) in the glassy state increases by 23.8% compared with the neat epoxy (28.00 GPa). The possible mechanism for enhanced flame retardant and mechanical performances is proposed according to the test results. This work has opened up a new application for AGO@COF nanohybrid in the field of flame-retardant polymers.

引用

页数：11

共 53 条

[11] Preparation of mixed matrix membranes based on polyimide and aminated graphene oxide for CO2 separation [J].

Ge, Bao-Sheng ;

Wang, Tao ;

Sun, Hai-Xiang ;

Gao, Wen ;

Zhao, Hao-Ru .

POLYMERS FOR ADVANCED TECHNOLOGIES, 2018, 29 (04) :1334-1343

[12] A triazine-based covalent organic polymer for efficient CO2 adsorption [J].

Gomes, Ruth ;

Bhanja, Piyali ;

Bhaumik, Asim .

CHEMICAL COMMUNICATIONS, 2015, 51 (49) :10050-10053

[13] Approximate analytical solutions for transient mass flux and ignition time of solid combustibles exposed to time-varying heat flux [J].

Gong, Junhui ;

Li, Yabo ;

Chen, Yixuan ;

Li, Jing ;

Wang, Xuan ;

Jiang, Juncheng ;

Wang, Zhirong ;

Wang, Jinghong .

FUEL, 2018, 211 :676-687

[14] In situ preparation of reduced graphene oxide/DOPO-based phosphonamidate hybrids towards high-performance epoxy nanocomposites [J].

Guo, Wenwen ;

Yu, Bin ;

Yuan, Yao ;

Song, Lei ;

Hu, Yuan .

COMPOSITES PART B-ENGINEERING, 2017, 123 :154-164

[15] In-situ synthesized CNTs/Bi2Se3 nanocomposites by a facile wet chemical method and its application for enhancing fire safety of epoxy resin [J].

Hou, Yanbei ;

Hu, Weizhao ;

Liu, Longxiang ;

Gui, Zhou ;

Hu, Yuan .

COMPOSITES SCIENCE AND TECHNOLOGY, 2018, 157 :185-194

[16] PREPARATION OF GRAPHITIC OXIDE [J].

HUMMERS, WS ;

OFFEMAN, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339

[17] Overview of Nonflammability Characteristics of Graphene and Graphene Oxide-Based Polymeric Composite and Essential Flame Retardancy Techniques [J].

Kausar, Ayesha ;

Anwar, Zanib ;

Muhammad, Bakhtiar .

POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2017, 56 (05) :488-505

[18] Preparation of a silica nanospheres/graphene oxide hybrid and its application in phenolic foams with improved mechanical strengths, friability and flame retardancy [J].

Li, Xiaoyan ;

Wang, Zhengzhou ;

Wu, Lixin .

RSC ADVANCES, 2015, 5 (121) :99907-99913

[19] Controllable preparation of core-shell magnetic covalent-organic framework nanospheres for efficient adsorption and removal of bisphenols in aqueous solution [J].

Li, Yang ;

Yang, Cheng-Xiong ;

Yan, Xiu-Ping .

CHEMICAL COMMUNICATIONS, 2017, 53 (16) :2511-2514

[20] Covalent assembly of MCM-41 nanospheres on graphene oxide for improving fire retardancy and mechanical property of epoxy resin [J].

Li, Zhi ;

Jimenez Gonzalez, Alejandro ;

Babu Heeralal, Vignesh ;

Wang, De-Yi .

COMPOSITES PART B-ENGINEERING, 2018, 138 :101-112

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