Electrophilic substitution Ni(II)→M(II) in Ni2[Fe(CN)6] gelatin-immobilized matrix materials

被引：6

作者：

Tatarintseva, TB ^{[1
]}

Mikhailov, OV ^{[1
]}

Naumkina, NI ^{[1
]}

Yusupov, RA ^{[1
]}

机构：

[1] Kazan State Univ Technol, Kazan, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2003年 / 73卷 / 06期

关键词：

D O I：

10.1023/A:1026328129296

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrophilic substitution reactions Ni(II)-->M(II) (M = Co, Cu, Zn, Cd) occurring in nickel(II) hexacyanoferrate(II) gelatin-immobilized matrix materials on their contact with aqueous solutions of corresponding chlorides MCl were studied. During contact, Ni(II) is partly substituted by the other metal to form heteronuclear hexacyanofeffates(II) of nickel(II) and corresponding double-charged ions, and none of the studied reactions involves complete substitution of Ni(II) until the mononuclear hexacyanoferrate(II) M-2[Fe(CN)(6)] has formed.

引用

页码：847 / 854

页数：8

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